A new coating based on polymer-derived ceramics (PDC), oxides and refractory ceramic with a thickness of around 50 µm has been developed to improve the resistance corrosion of stainless steel substrate against molten aluminum alloy in a thermal energy storage (TES) system designed to run at high temperature (up to 600 °C). These coatings implemented by straightforward methods, like tape casting or paintbrush, were coated on planar and cylindrical stainless-steel substrates, pyrolyzed at 700 °C before being plunged for 600 and 1200 h in molten AlSi12 at 700 °C. The stainless-steel substrate appears healthy without intermetallic compounds, characteristic of molten aluminum alloy corrosion. The protective coating against AlSi12 corrosion shows excellent performance and appears interesting for TES applications.
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