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The objective of this paper is to provide new data about the possibility of using ammonia as a carbon-free fuel in a spark-ignition engine. A current GDI PSA engine (Compression Ratio 10.5:1) was chosen in order to update the results available in the literature mainly obtained in the CFR engine. Particular attention was paid to determine the lowest possible load limit when the engine is supplied with pure ammonia or a small amount of H2, depending on engine speed, in order to highlight the limitation during cold start conditions. It can be concluded that this engine can run stably in most of these operating conditions with less than 10% H2 (of the total fuel volume) added to NH3. Measurements of exhaust pollutants, and in particular NOx, have made it possible to evaluate the possibility of diluting the intake gases and its limitation during combustion with pure H2 under slightly supercharged conditions. In conclusion, the 10% dilution limit allows a reduction of up to 40% in NOx while guaranteeing stable operation.

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Recent studies concluded that the use of ammonia in SI engines is possible thanks to an ignition booster or promoter. In this paper, the improvement of premixed ammonia/air combustion for internal combustion engines is studied as a function of performance and exhaust pollutants in a Spark-Assisted Compression Ignition single-cylinder engine, which supports a higher compression ratio (CR). For the first time, pure NH3 combustion was performed over a large range of engine operating conditions. The study concludes that neat ammonia can be used over a large operating range, here driven by the intake pressure, using a classical ignition device with a CR of 14–17 at 1000 rpm. The comparison with previous data obtained in a current single-cylinder SI engine clearly shows the potential of this engine mode, even for very low loads and various engine speeds (650, 1000, 2000 rpm), in spite of an initial aerodynamic that is not optimized to enhance flame-turbulence interaction. Kinetic simulations provide some explanations about exhaust emission behaviour, especially unburnt NH3, H2, NOx and N2O.