Recent progress with microfabricated quantum devices has revealed that an ubiquitous source of noise originates in tunneling material defects that give rise to a sparse bath of parasitic two-level systems (TLSs). For superconducting qubits, TLSs residing on electrode surfaces and in tunnel junctions account for a major part of decoherence and thus pose a serious roadblock to the realization of solid-state quantum processors. Here, we utilize a superconducting qubit to explore the quantum state evolution of coherently operated TLSs in order to shed new light on their individual properties and environmental interactions. We identify a frequency-dependence of TLS energy relaxation rates that can be explained by a coupling to phononic modes rather than by anticipated mutual TLS interactions. Most investigated TLSs are found to be free of pure dephasing at their energy degeneracy points, around which their Ramsey and spin-echo dephasing rates scale linearly and quadratically with asymmetry energy, respectively. We provide an explanation based on the standard tunneling model, and identify interaction with incoherent low-frequency (thermal) TLSs as the major mechanism of the pure dephasing in coherent high-frequency TLS.

The study and prediction of chemical reactivity is one of the most important application areas of molecular quantum chemistry. Large-scale, fully error-tolerant quantum computers could provide exact or near-exact solutions to the underlying electronic structure problem with exponentially less effort than a classical computer thus enabling highly accurate predictions for comparably large molecular systems. In the nearer future, however, only "noisy" devices with a limited number of qubits that are subject to decoherence will be available. For such near-term quantum computers the hybrid quantum-classical variational quantum eigensolver algorithm in combination with the unitary coupled-cluster ansatz (UCCSD-VQE) [1,2] has become an intensively discussed approach that could provide accurate results before the dawn of error-tolerant quantum computing. In this work we present an implementation of UCCSD-VQE that allows for the first time to treat both openand closed-shell molecules. We study the accuracy of the obtained energies for nine small molecular systems as well as for four exemplary chemical reactions by comparing to well-established electronic structure methods like (non-unitary) coupled-cluster and density functional theory. Finally, we roughly estimate the required quantum hardware resources to obtain "useful" results for practical purposes.

We consider superconducting circuits for the purpose of simulating the spin-boson model. The spin-boson model consists of a single two-level system coupled to bosonic modes. In most cases, the model is considered in a limit where the bosonic modes are sufficiently dense to form a continuous spectral bath. A very well known case is the ohmic bath, where the density of states grows linearly with the frequency. In the limit of weak coupling or large temperature, this problem can be solved numerically. If the coupling is strong, the bosonic modes can become sufficiently excited to make a classical simulation impossible. Here, we discuss how a quantum simulation of this problem can be performed by coupling a superconducting qubit to a set of microwave resonators. We demonstrate a possible implementation of a continuous spectral bath with individual bath resonators coupling strongly to the qubit. Applying a microwave drive scheme potentially allows us to access the strongcoupling regime of the spin-boson model. We discuss how the resulting spin relaxation dynamics with different initialization conditions can be probed by standard qubit-readout techniques from circuit quantum electrodynamics.

The sensitivity of superconducting qubits allows for spectroscopy and coherence measurements on individual two-level systems present in the disordered tunnel barrier of an Al/AlOx/Al Josephson junction. We report experimental evidence for the decoherence of two-level systems by Bogoliubov quasiparticles leaking into the insulating AlOx barrier. We control the density of quasiparticles in the junction electrodes either by the sample temperature or by injecting them using an on-chip dc-SQUID driven to its resistive state. The decoherence rates were measured by observing the two-level system's quantum state evolving under application of resonant microwave pulses and were found to increase linearly with quasiparticle density, in agreement with theory. This interaction with electronic states provides a noise and decoherence mechanism that is relevant for various microfabricated devices such as qubits, single-electron transistors, and field-effect transistors. The presented experiments also offer a possibility to determine the location of the probed two-level systems across the tunnel barrier, providing clues about the fabrication step in which they emerge. I: INTRODUCTIONWhile superconducting circuits based on Josephson junctions (JJs) rapidly mature towards favorable and applicable qubits for quantum computers [1-3], a major source of their decoherence traces back to spurious material defects that give rise to the formation of low-energy two-level systems (TLSs). On the other hand, sensitivity to tiny perturbations turns JJ qubits into ideal tools to study the properties of TLSs. For example, microwave spectroscopy of JJ phase qubits shows avoided level crossings revealing the TLSs' quantum character as well as their coherent interaction with the qubit [4]. Various microscopic models including dangling bonds, Andreev bound states [5], and Kondo fluctuators [6] have been suggested to explain the origin of TLSs. There is growing evidence [7,8], however, that they are formed by small groups of atoms that are able to tunnel between two energetically almost equivalent configurations. This is most strongly supported by recent experiments where the TLSs' energy splittings were tuned by applying external static strain [9]. TLSs are the source of lowenergy excitations, which are also responsible for the thermal, acoustic, and dielectric properties of glasses at temperatures below 1 K [10,11], which are well studied in bulk materials. Inherent to disordered solids, they are present in surface oxides and insulating layers of any microfabricated device as well as in the tunnel barriers of Josephson junctions.In contrast to traditional measurements performed on glasses that probe huge ensembles of TLSs, the sensitivity of JJ-based qubits allows one to address single TLSs and determine their individual properties. Strain-tuning experiments, e.g., measure a TLS's deformation potential [9] and allow for a detailed analysis of the coherent interaction between two TLSs brought into resonance [12]. In another experiment, the temperatu...

Digital quantum simulations offer exciting perspectives for the study of fermionic systems such as molecules or lattice models. However, with quantum error correction still being out of reach with present-day technology, a non-vanishing error rate is inevitable. We study the influence of gate errors on simulations of the Trotterized time evolution of the quantum system with focus on the fermionic Hubbard model. Specifically, we consider the effect of stochastic over-rotations in the applied gates. Depending on the particular algorithm implemented such gate errors may lead to a time evolution that corresponds to a disordered fermionic system, or they may correspond to unphysical errors, e.g., violate particle number conservation. We substantiate our analysis by numerical simulations of model systems. In addition we establish the relation between the gate fidelity and the strength of the over-rotations in a Trotterized quantum simulation. Based on this we provide estimates for the maximum number of Trotter steps which can be performed with sufficient accuracy for a given algorithm. This in turn implies, apart from obvious limitations on the maximum time of the simulation, also limits on the system size which can be handled.