Hydrogels are an interesting class of materials used in extrusion-based 3D printing, e.g., for drug delivery or tissue engineering. However, new hydrogel formulations for 3D printing as well as a detailed understanding of crucial formulation properties for 3D printing are needed. In this contribution, hydrogels based on poly(ethylene glycol) diacrylate (PEG-DA) and the charged monomers 3-sulfopropyl acrylate and [2-(acryloyloxy)ethyl]trimethylammonium chloride are formulated for 3D printing, together with Poloxamer 407 (P407). Chemical curing of formulations with PEG-DA and up to 5% (w/w) of the charged monomers was possible without difficulty. Through careful examination of the rheological properties of the non-cured formulations, it was found that flow properties of formulations with a high P407 concentration of 22.5% (w/w) possessed yield stresses well above 100 Pa together with pronounced shear thinning behavior. Thus, those formulations could be processed by 3D printing, as demonstrated by the generation of pyramidal objects. Modelling of the flow profile during 3D printing suggests that a plug-like laminar flow is prevalent inside the printer capillary. Under such circumstances, fast recovery of a high vicosity after material deposition might not be necessary to guarantee shape fidelity because the majority of the 3D printed volume does not face any relevant shear stress during printing.
The increasing requirements on plastic parts demand a rising use of combined functional and reinforcing materials. Therefore, often reinforcing particles with different aspect ratios are added to the plastic as additive mixtures. However, the engineering design process of reinforced parts requires an early knowledge of the expected orientation of the reinforcing particles. Numerous models try to predict the orientation of particles in polymer suspensions. However, the interaction coefficient strongly depends on the aspect ratio of the particles and a prediction of the orientation behavior of additive mixtures with differently shaped particles has not been validated using conventional methods. In this work, the orientation of differently shaped particle mixtures in polymer suspensions is investigated for different fluid channel geometries. Finally, the Folgar–Tucker model is applied to filler mixtures and implemented into OpenFOAM®, which enables the comparison of filler orientation in different fluid channel geometries. Regarding the experiments a characteristic increase of the interaction coefficient was observed at a filling level of 5%. Furthermore, it was shown that a balanced mixing ratio yields higher interaction coefficients. With regard to the performed simulations, it was possible to show qualitatively how a considered interaction between fibers and platelets affects the orientations.
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