Phase transformations greatly affect physical properties of rocks and impose a first-order control on geodynamic processes. Under high deformation rates, rheological heterogeneities cause large spatial variations of stress in materials. Until now, the impact of higher deformation rates, rock heterogeneity and stress build up on phase transformations and material properties is not well understood. Here we show, that phase transitions are controlled by the stress build-up during fast deformation. In a deformation experiment (600 °C, 1.47 GPa), rock heterogeneity was simulated by a strong elliptical alumina inclusion in a weak calcite matrix. Under deformation rates comparable to slow earthquakes, calcite transformed locally to aragonite matching the distribution of maximum principal stresses and pressure (mean stress) from mechanical models. This first systematic investigation documents that phase transformations occur in a dynamic system during deformation. The ability of rocks to react during fast deformation rates may have serious consequences on rock rheology and thus provide unique information on the processes leading to giant ruptures in subduction zones.

<p>Phase transitions affect the physical properties of rocks (e.g. rheology) and control geodynamic processes at different spatial and time scales. However, the influence of deformation on phase transitions and their coupling is not well understood. <br>Previous experiments, with both assembly-induced and additionally placed mechanical heterogeneities, have shown patterns in the phase transition distribution. Numerical modelling (2D, viscous finite difference models) have been used to correlate the experimental observations with the mechanic stress state. The locally increased mean stress in the models shows the best correlation with the formation of high-pressure polymorphs in experiments (Cionoiu et al. 2019).<br>Besides the distribution of polymorphs, grain-size and deformation patterns also vary across the samples due to stress, strain and pressure variations. To better understand the mechanisms contributing to these variations, we used advanced numerical models (3D, viscoelastic) to calculate the local distribution of first order parameters as pressure, stress and strain. The modelled stress and strain patterns are compared to the experimentally produced phase transformation distribution and previous (2D) modelling results. The 2D and 3D models differ partially regarding the quantification of local stresses – an effect that mainly depends on sample geometry (coaxial vs. general-shear). However, the qualitative fit between experiments, 2D and 3D models persists (i.e. the localisation of increased stresses or strain).<br>This contribution shows how numerical models, that closely represent the sample, can further improve the understanding of processes occurring in deformation experiments. Our new results emphasize that mechanically-induced stress-variations influence the grain-size and mineralogy of rocks which feeds back on their rheology.</p><p>References: <br>Cionoiu, S., Moulas, E. & Tajčmanová, L. Impact of interseismic deformation on phase transformations and rock properties in subduction zones. Sci Rep 9, 19561 (2019)</p>

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Understanding conditions in the Earth's interior requires data derived from laboratory experiments. Such experiments provide important insights into the conditions under which mineral reactions take place as well as processes that control the localization of deformation in the deep Earth. We performed Griggs‐type general shear experiments in combination with numerical models, based on continuum mechanics, to quantify the effect of evolving sample geometry of the experimental assembly. The investigated system is constituted by CaCO3 and the experimental conditions are near the calcite‐aragonite phase transition. All experimental samples show a heterogeneous distribution of the two CaCO3 polymorphs after deformation. This distribution is interpreted to result from local stress variations. These variations are in agreement with the observed phase‐transition patterns and grain‐size gradients across the experimental sample. The comparison of the mechanical models with the sample provides insights into the distribution of local mechanical parameters during deformation. Our results show that, despite the use of homogeneous sample material (here calcite), stress variations develop due to the experimental geometry. The comparison of experiments and numerical models indicates that aragonite formation is primarily controlled by the spatial distribution of mechanical parameters. Furthermore, we monitor the maximum pressure and σ1 that is experienced in every part of our model domain for a given amount of time. We document that local pressure (mean stress) values are responsible for the transformation. Therefore, if the role of stress as a thermodynamic potential is investigated in similar experiments, an accurate description of the state of stress is required.