This is considered to take place in a density-stratified reservoir, with alkali basalt magmas at the base and hydrous trachytes forming an upper cap or cupola. The presence of this reservoir at shallow crustal depths beneath the caldera likely inhibits the ascent and subsequent eruption of mafic magmas, generating a compositional Daly Gap. Rare syenitic ejecta represent in situ crystallisation of trachytic magmas in the thermal boundary zone at the top of the reservoir. Trachytic enclaves within these syenites, in addition to banded pumices and ubiquitous clinopyroxene antecrysts in the UFG pumice falls, provide evidence for mingling/mixing processes within the magmatic system. Despite relatively uniform major element compositions, systematic trace element variations within individual eruptions highlight the importance of fractional crystallisation during late-stage evolution of the trachytes. This is facilitated by the accumulation of water and the development of mild peralkalinity, which contribute to low pre-eruptive melt viscosities and efficient crystal settling. Compositional zoning patterns between individual eruptions cannot be accounted for by periodic tapping of a single magma batch undergoing fractional crystallisation. Instead, up to four individual cycles are recognised, in which a zoned cap of eruptible trachytic magma, formed at the top of the reservoir, was erupted in one or more eruptions and was re-established via intermittent replenishment and subsequent fractional crystallisation. Keywords Furnas volcano · Peralkaline trachyte · Fractional crystallisation · Zoned magma reservoir · Post-caldera volcanismAbstract Furnas is one of three active central volcanoes on São Miguel Island, Azores, and is considered to be one of the most hazardous in the archipelago. In this study, the pre-eruptive magma plumbing system of the 10 young (<5 ka), intra-caldera, sub-Plinian, trachytic eruptions of the Upper Furnas Group (UFG) is investigated via whole rock major and trace element geochemistry, mineral chemistry, thermobarometry, and petrogenetic modelling. The main aim of this work is to elucidate the petrogenesis of the Furnas trachytes, constrain the P-TfO 2 conditions under which they evolve, and investigate the temporal evolution of the magma plumbing system. Results indicate that the trachytes are derived predominantly from extended fractional crystallisation of alkali basalt parental magmas, at depths between ~3 and 4 km.Communicated by Jochen Hoefs. Electronic supplementary materialThe online version of this article

Interaction between magma and crustal carbonate at active arc volcanoes has recently been proposed as a source of atmospheric CO 2 , in addition to CO 2 released from the mantle and subducted oceanic crust. However, quantitative constraints on efficiency and timing of these processes are poorly established. Here, we present the first in situ carbon and oxygen isotope data of texturally distinct calcite in calc-silicate xenoliths from arc volcanics in a case study from Merapi volcano (Indonesia). Textures and C-O isotopic data provide unique evidence for decarbonation, magma-fluid interaction, and the generation of carbonate melts. We report extremely light δ 13 C PDB values down to −29.3‰ which are among the lowest reported in magmatic systems so far. Combined with the general paucity of relict calcite, these extremely low values demonstrate highly efficient remobilisation of crustal CO 2 over geologically short timescales of thousands of years or less. This rapid release of large volumes of crustal CO 2 may impact global carbon cycling.

Magma-carbonate interaction is an increasingly recognised process occurring at active volcanoes worldwide, with implications for the magmatic evolution of the host volcanic systems, their eruptive behaviour, volcanic CO2 budgets, and economic mineralisation. Abundant calc-silicate skarn xenoliths are found at Merapi volcano, Indonesia. We identify two distinct xenolith types: magmatic skarn xenoliths, which contain evidence of formation within the magma, and exoskarn xenoliths, which more likely represent fragments of crystalline metamorphosed wall-rocks. The magmatic skarn xenoliths comprise distinct compositional and mineralogical zones with abundant Ca-enriched glass (up to 10 wt% relative to lava groundmass), mineralogically dominated by clinopyroxene (En15-43Fs14-36Wo41-51) + plagioclase (An37-100) ± magnetite in the outer zones towards the lava contact and by wollastonite ± clinopyroxene (En17-38Fs8-34Wo49-59) ± plagioclase (An46-100) ± garnet (Grs0-65Adr24-75Sch0-76) ± quartz in the xenolith cores. These zones are controlled by Ca transfer from the limestone protolith to the magma and by transfer of magma-derived elements in the opposite direction. In contrast, the exoskarn xenoliths are unzoned and essentially glass-free, representing equilibration at sub-solidus conditions. The major mineral assemblage in the exoskarn xenoliths is wollastonite + garnet (Grs73-97Adr3-24) + Ca-Al-rich clinopyroxene (CaTs0-38) + anorthite ± quartz, with variable amounts of either quartz or melilite (Geh42-91) + spinel. Thermobarometric calculations, fluid inclusion microthermometry and newly calibrated oxybarometry based on Fe3+/ΣFe in clinopyroxene indicate magmatic skarn xenolith formation conditions of ∼850 ± 45 °C, &lt; 100 MPa and at an oxygen fugacity between the NNO and HM buffer. The exoskarn xenoliths, in turn, formed at 510-910 °C under oxygen fugacity conditions between NNO and air. These high oxygen fugacities are likely imposed by the large volumes of CO2 liberated from the carbonate. Halogen and sulphur-rich mineral phases in the xenoliths testify to the infiltration by a magmatic brine. In some xenoliths this is associated with the precipitation of copper-bearing mineral phases by sulphur dissociation into sulphide and sulphate, indicating potential mineralisation in the skarn system below Merapi. Compositions of many xenolith clinopyroxene and plagioclase crystals overlap with that of magmatic minerals, suggesting that the crystal cargo in Merapi magmas may contain a larger proportion of skarn-derived xenocrysts than previously recognised. Assessment of xenolith formation timescales demonstrates that magma-carbonate interaction and associated CO2 release could affect eruption intensity, as recently suggested for Merapi and similar carbonate-hosted volcanoes elsewhere.

No abstract