A highly active graphitic C 3 N 4 photocatalyst prepared from a mixture of urea and melamine with advanced structural, optical and electronic properties and enhanced photocatalytic activity for the production of hydrogen gas is explored. The prepared photocatalyst is able to generate a high rate of hydrogen gas production (135 mmol h À1 ) by loading with 1 wt% Pt as a co-catalyst. The good separation of C 3 N 4 sheets, lower recombination rate of excitons and the high amount of generated photocurrent have significantly contributed towards the photocatalytic activity of graphitic carbon nitride prepared from a mixture of urea and melamine.C 3 N 4 -M and C 3 N 4 -MU, stability test of C 3 N 4 -MU photoelectrode, mechanism of photocurrent generation over n-type g-C 3 N 4 photoelectrode, characterisation techniques i.e. XRD, optical absorbance spectra, FT-IR spectra and photocatalytic activity for hydrogen production of graphitic C 3 N 4 prepared by taking melamine and urea with molar ratios of 1 : 2 and 2 : 1. See
Noble‐metal Au nanoparticles deposited on graphitic carbon nitride polymer (g‐C3N4) photocatalyst by a facile deposition–precipitation method exhibited high photocatalytic activity for hydrogen gas production under visible‐light irradiation. The Au/g‐C3N4 nanocomposite plasmonic photocatalysts were characterized by X‐ray diffraction spectroscopy, diffuse reflectance UV/Vis spectroscopy, FTIR spectroscopy, field‐emission scanning electron microscopy, high‐resolution transmission electron microscopy, selected‐area electron diffraction, X‐ray photoelectron spectroscopy, photoluminescence spectroscopy, and photoelectrochemical measurements. We studied the effect of Au deposition on the photocatalytic activity of g‐C3N4 by investigation of optical, electronic, and electrical properties. Enhanced photocatalytic activity of Au/g‐C3N4 naocomposite for hydrogen production was attributed to the synergic mechanism operating between the conduction band minimum of g‐C3N4 and the plasmonic band of Au nanoparticles including high optical absorption, uniform distribution, and nanoscale particle size of gold. The mechanism of te photocatalytic activity of the nanocomposite photocatalyst is discussed in detail. Deposition of Au nanoparticles on g‐C3N4 was optimized and it was found that 1 wt % Au‐loaded g‐C3N4 composite plasmonic photocatalyst generated a photocurrent density of 49 mA cm−2 and produced a hydrogen gas amount of 532 μmol under visible light, which were more than 3000 times higher and 23 times higher, respectively, than the values of neat g‐C3N4.
With the purpose of efficient electron-hole separation and enhancement of photocatalytic performance in the visible region, we have fabricated a novel p-BiOI/n-ZnTiO3 heterojunction by a precipitation-deposition method and studied its activity toward dye degradation. The physicochemical characteristics of the fabricated BiOI/ZnTiO3 heterojunctions were surveyed by powder X-ray diffraction pattern (PXRD), BET-surface area, diffuse reflectance UV-vis (DRUV-vis), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), photoluminescence spectroscopy (PL spectra), X-ray photoelectron spectroscopy (XPS), and photoelectrochemical measurement. The photosensitization effect of BiOI enhanced the spectral response of ZnTiO3 from UV to visible region, making all the BiOI/ZnTiO3 heterojunctions active under visible light. The PEC measurement confirmed the p-type character of BiOI and n-type character of ZnTiO3. The optimal amount of BiOI in BiOI/ZnTiO3 heterojunctions was found to be 50% which degraded 82% of 50 ppm Rh 6G under visible light irradiation. The degradation rate of 50% BiOI/ZnTiO3 heterojunction was found to be 9.8 and 11.1 times higher than that of bare BiOI and ZnTiO3, respectively. The photosensitization effect of BiOI and the formed heterojunction between p-type BiOI and n-type ZnTiO3 contribute to improved electron-hole separation and enhancement in photocatalytic activity.
Fast recombination
of photoinduced charge carriers is a major problem
in the case of semiconductor based photocatalysts, which must be solved
for their potential application in photocatalysis. In this work, photostable
CdS QDs/BiOI composites have been successfully fabricated by a two-step
precipitation–deposition method. The prepared samples were
characterized by X-ray diffraction (XRD), UV–vis diffuse reflection
spectroscopy (UV–vis DRS), photoluminescence (PL) spectroscopy,
transmission electron microscopy (TEM), X-ray photoelectron spectroscopy
(XPS), Mott–Schottky, and electrochemical impedance analysis.
The potential applications of CdS QDs/BiOI composite materials have
been tested toward decolorization of rhodamine B (RhB) solution and
hydrogen generation under solar light and visible light irradiation,
respectively. It has been observed that hydroxyl radicals, electrons,
and holes played a major role in decolorization of RhB solution. Among
all prepared photocatalysts, 4% CdS QDs/BiOI composite was able to
decolorize 82% of RhB solution in 1 h and 203 μmol/h of H2 under solar light and visible light irradiation, respectively.
The highest activity has been ascribed to optimal loading of CdS QDs,
good formation of composites, and the lowest recombination of charge
carriers.
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