[reaction: see text] The aza-Henry reaction of imines with nitroalkanes was promoted by chiral thiourea with an N,N-dimethylamino group to give beta-nitroamines with good enantioselectivity. Various N-protected imines were examined as substrates. N-Phosphinoylimine gave the best result in terms of chemical yield and enantioselectivity (up to 91% yield, up to 76% ee).
An overview of steady state tokamak studies in TRIAM-1M (R0 = 0.8 m, a × b = 0.12 m × 0.18 m and B = 8 T) is presented. The current ramp-up scenario without using centre solenoid coils is reinvestigated with respect to controllability of the current ramp-up rate at the medium density region of (1–2) × 1019 m−3. The plasma is initiated by ECH (fundamental o-mode at 170 GHz with 200 kW) at B = 6.7 T, and the ramp-up rate below the technical limit of 150 kA s−1 for ITER can be achieved by keeping the LH power less than 100 kW during the current ramp-up phase. The physics understanding of the enhanced current drive (ECD) mode around the threshold power level has progressed from a viewpoint of transition probability. A transition frequency, ftrans, for the ECD transition is determined as a function of PCD. At ∼70 kW no transition occurs for an ftrans value of ∼0.017 Hz, meaning almost zero transition probability. With increasing PCD > Pth, ftrans increases up to 10 Hz, and the transition tends to occur with high probability. The record value of the discharge duration is updated to 3 h 10 min in a low
and low power (<10 kW) discharge. The global particle balance in long duration discharges is investigated, and the temporal change in wall pumping rate is determined. Although the density was low, the gas supply had to be stopped at 30 min after the plasma initiation to maintain the density constant. After that the density was sustained by the recycling flux alone until the end of the discharges. In addition to the recycling problem, in the high power and high density experiments, the localized PWI affects the SSO of the tokamak plasma. The effects of enhanced influx of metal impurities (Fe, Cr, Ni, Mo) on sustainment of the high performance ECD plasma are investigated. In order to evaluate the helium bombarding effects on the plasma facing component and hydrogen recycling in the future burning plasma, microscopic damage of metals exposed to long duration helium discharges was studied. The total exposure time was 128 s. From thermal desorption experiments for the specimens the amount of retained helium was evaluated as 3.9 × 1020 He m−2 and the scale length to be ∼1 mm in the SOL.
We assessed the outcome of tendon grafting of multiple finger extensor tendon ruptures in 14 patients with rheumatoid arthritis. Extensor lags improved from a preoperative mean of 33 degrees (range, 20 degrees-65 degrees) to a postoperative mean of 18 degrees (range, 0-60 degrees). However, loss of finger flexion was observed, with a mean postoperative fingertip to palm distance of 1.6 (range: 0-7.5) cm. Patient satisfaction correlated with the fingertip to palm distance, though not with the postoperative extensor lag. Because of the loss of finger flexion which was probably due to muscle contracture, we conclude that the results of tendon grafts in this situation are unsatisfactory.
ABSTRACT. Seroprevalence of Bartonella henselae and Toxoplasma gondii was investigated among 471 pet cats obtained from seven private animal hospitals in Kanagawa and Saitama Prefectures during the period from May 1994 to June 1995. Furthermore, 67 randomly selected from the 471 serum samples were examined for the feline immunodeficiency virus (FIV) antibody and feline leukemia virus (FeLV) antigen. The antibody to B. henselae was examined by an indirect immunofluorecent antibody test. T. gondii, FIV and FeLV infections in cats were detected with respective commercial kits. Of the cat serum samples tested, 43 (9.1%) were found to be seropositive for B. henselae and 41 (8.7%) for T. gondii. The B. henselae-positive rate (12.9%) of male cats was significantly higher than that (5.2%) of female cats. On the other hand, T. gondii-positive rate was 9.1% in male and 8.7% in female cats and there was no significant difference in the positivity between sexes. The positive rate in each hospital varied from 0 to 19.5% for B. henselae and 4.9 to 18.8% for T. gondii. The ages of B. henselae-and T. gondii-positive cats were distributed from <1-year-old to 14-year-old and the seropositivity increased with age of cats. Of the 67 cat serum samples, 16 and 6 cases were positive for FIV and FeLV, respectively. There was no relationship between these viral and B. henselae infections in cats. -KEY WORDS:
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