CuO-TiO2 nanocomposites were successfully synthesized using the C. benghalensis plant extracts. The effect of the composition of CuO to TiO2 on the morphological, optical, electrochemical, and photodegradation efficiency in the composites was studied. SEM, XRD, UV-vis, FTIR, TGA, BET, and CV were used to characterize these materials. The XRD data reported the tenorite structure of the CuO and the anatase phase of the TiO2. SEM showed the spherical morphologies for all the CuO-TiO2 NPs, and these were also mesoporous in nature, as depicted by BET. The voltammogram of the CuO-TiO2 30/70 electrode showed a higher response current density compared to the other two samples, suggesting a higher specific capacitance. Upon testing the photocatalytic efficiencies of the CuO-TiO2 nanocomposites against methylene blue (MB), ciprofloxacin (CIP), and sulfisoxazole (SSX), the highest degradation of 94% was recorded for SSX using the CuO-TiO2 30/70 nanocomposites. Hydroxyl radicals were the primary species responsible for the photodegradation of SSX, and the material could be reused once. The most active species in the photodegradation of SSX has been identified as OH•. From this study, it can be noted that the CuO-TiO2 nanocomposites were more selective toward the degradation of antibiotics (sulfisoxazole and ciproflaxin) as compared to dyes (methylene blue).
The quest for eco-friendly synthetic routes that can be used for the development of multifunctional materials, in particular for water treatment, has reinforced the use of plant extracts as replacement solvents. In this study, bimetallic ZnOSnO2 nanoparticles of different ratios were synthesized using the Sutherlandia frutescens (S. frutescens) plant and tested for the degradation of methylene blue dye and the antibiotics sulfisoxazole and sulfamethoxazole. From the analysis, FTIR confirmed the formation of bimetallic nanoparticles in all ratios within the fingerprint region. SEM revealed homogenous and heterostructures of tubular and spherical structures, with the size distribution ranging from 5–60 nm, respectively. XRD confirmed the formation and the crystallinity of the bimetallic nanoparticles, UV-Vis confirmed the optical properties of the materials and the bandgap values were found between 3.08 and 3.3 eV. From the surface area analysis, type III isotherm and mesoporous structures were confirmed. The photocatalytic activity of these ratios was investigated against MB dye and the antibiotics SSX and SMX. The highest degradation of 88% for MB was obtained using the 50:50 loading ratio at 150 min with a fast kinetic rate of 0.0008 min−1. Furthermore, the holes were the species found to be responsible for the degradation of MB. The SSX and SMX antibiotics exhibited a 66% and 70% degradation, respectively. From this analysis, it can be noted that it is possible to synthesize environmentally safe materials that can be used to degrade various pollutants in our water streams.
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