In the current study, a set of 60 glass tesserae from two disrupted Roman mosaics located in Pordenone and Trento (northeastern Italy) are analyzed, with the aim of investigating the coloring and opacification techniques, with a focus on the causes of specific textural features. All the available colors and textures were selected for archaeometric analyses, in order to guarantee the full characterization of both assemblages and comparisons between the two sites. The applied analytical protocol comprises micro-textural and preliminary chemical characterizations of the tesserae by means of OM and SEM-EDS, mineralogical analysis of the opacifiers by XRD and chemical analysis of the glassy matrices by EPMA; in addition, on specific tesserae, micro-Raman spectroscopy, FORS, and EPR were also performed to clarify the type of opacifer, coloring ion and oxidation state, respectively. Results show that both the base-glass and the coloring/opacification techniques identified are consistent with the presumed Roman dating of the mosaics. All the tesserae are natron-based and chemically comparable with major Roman compositional groups, except for red samples. Antimony-based opacifiers are identified in most of the blue, turquoise, white, yellow and green tesserae, and copper-based opacifiers in the red ones; cobalt and copper are the most frequent ionic colorants used to obtain various shades of blue, turquoise and green colors. Despite the general comparability of both assemblages with the published data on glass tesserae coeval in age, the present study shows differences in the technological solutions used for obtaining the same color, and less common coloring and opacification techniques in three samples from Pordenone. The banded textures of some tesserae were also carefully investigated, and multiple factors influencing the changes in color (different distribution or relative abundance of opacifiers, crystal size, micro-texture, chemical composition of glassy matrix) are identified.

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Introduction: The present study focuses on Late-Roman/Early Medieval glass found in the productive area within the ancient harbour of Classe near Ravenna, one of the most important trade centres between the 5 th and 8 th centuries AD of the Northern Adriatic area. Aims of the study were the identification of the main glass compositions and their contextualisation in Late-Antique groups; the identification of provenance of raw glass, and, consequently, of commercial routes; the extent, if any, of recycling glass cullet, as an alternative to the import of fresh raw glass; the identification of possible connections between archaeological typology and glass chemical composition.Results: 32 glassworking wastes and 25 drinking vessel fragments for a total amount of 57 fragments were devoted to chemical analysis in XRF and EPMA. All the analysed fragments are silica-soda lime glasses, produced with natron as a flux, and are compositionally similar to Late-Antique groups HIMT, Série 3.2 and Levantine1. Raw glass chunks, glassworking wastes and objects of comparable compositions are identified into HIMT and Série 3.2 groups, while the Levantine 1 group includes only objects and glassworking wastes. Systematic comparisons between Classe and Aquileia, the two most important Late-Antique archaeological sites of North-Eastern Italy, were also carried out, and the same compositional groups were identified, although Série 3.2 in the Classe assemblage is more represented. Sr and Nd isotopic analysis confirmed that the composition of the three glasses derive from coastal sands of the Syro-Palestinian and Egyptian shore, with a slight shift in comparison to the published data. Little evidence of recycling was identified in the assemblage. Conclusions:In the 5 th century, a secondary glass workshop devoted to the shaping of glass vessels starting from raw glass chunks and, possibly, glass cullet, was active in the area of the harbour. Raw glass of HIMT and Série 3.2 was imported from the Levant and Egypt. Comparisons between Classe and Aquileia show that during the Late Antiquity these sites seem to be supplied of raw glass by the same trade routes. In addition, some connections between types and chemical compositions were highlighted.

The present paper focuses on the archaeometric characterisation of 38 glass tesserae of various colours from an in situ mosaic in Aquileia, Italy, dated to the second half of the fourth century AD. The examination of the textural, mineralogical and chemical features, conducted by means of a multi-methodological approach (optical microscopy (OM), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), electron probe micro analysis (EPMA), X-ray diffraction (XRD) and Fibre Optic Reflectance Spectrophotometer (FORS)), has provided valuable insights into the changes in the production technology during the transition between the Roman and the Late Antique periods. The assemblage is heterogeneous, and each chromatic group is composed of tesserae produced with different base glasses and colouring/opacifying techniques, suggesting diverse supplies. A small group of tesserae shows strict links to the Roman tradition in terms of both base glass and colouring/ opacifying techniques and was probably obtained by re-using tesserae from older mosaics. Conversely, a larger group of tesserae shows textural and chemical evidence of recycling and indicates the prompt use of Bnew^ opacifying technologies (such as the use of tin compounds) or uncommon technological solutions (such as the use of quartz and bubbles as opacifiers or the addition of metallurgical slags in red tesserae), suggesting a specific production in the fourth century AD

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