Phase stability and small-angle neutron scattering (SANS) data show that surfactant-stabilized nanodomains of a typical ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate [bmim][BF4]) may be dispersed by the nonionic surfactant Triton-X100 in cyclohexane. Analyses of these SANS data are consistent with the formation of ionic liquid-in-oil microemulsion droplets.

For some 15 years the attainment of efficient, nonfluorinated CO2-active surfactants has been a Holy Grail for researchers spanning pure and applied chemical sciences. This article tells the story of small-molecule CO2-active surfactants, from the first tentative observations with fluorinated compounds in 1991 up to recently discovered fluorine-free oxygenated amphiphiles.