Valencia(del inglés, Covalent Organic Framework) CC3-R que es un polímero orgánico poroso quiral descrito en la literatura. En este trabajo, se ha estudiado exhaustivamente por medio de 1 H-MAS-NMR, observándose que el COF denominado CC3-R, selectivamente interacciona preferentemente con moléculas Rquirales, siendo por tanto un material prometedor para la resolución quiral mediante métodos de adsorción selectiva. ABSTRACTThe present doctoral thesis focuses on studying new synthesis routes for the synthesis of porous materials, both inorganic and organic. In particular, this thesis is divided into two major chapters. The first chapter focuses on the study of porous inorganic materials, zeolites. In the development of this chapter, new organophosphate and phosphorous organic cations have been synthesized, which have been characterized and used as structure directing agents in the synthesis of zeolites. The use of synthesized phosphorated cations has allowed, for the first time, 1.4. BIBLIOGRAFIA 1. R. Dawson, A. I. Cooper, D. J. Adams, Progress in Polymer Science, 2012, 37, 530 2. A. V. Neimark, M. Thommes, Colloids and surfaces A: OBJETIVOS Capítulo 3 PROCEDIMIENTO EXPERIMENTAL Capítulo 3: Procedimiento Experimental 27 3.1. MATERIALES INORGÁNICOS POROSOS (ZEOLITAS) 3.1.1. REACTIVOS EMPLEADOS § 1,8-Naftalenimetanol> 95%, Key Organics § 1,2,4,5-Tetrakis (bromometil) benceno, 95%, Sigma -Aldrich § 1,2-bis (bromometil) benceno 97%, Sigma -Aldrich § Tribromuro de fósforo (PBr3) 97% ,Sigma-Aldrich § Diisopropil fosfina (iPr2PH) 10% en hexano, Acros § Trietilarsina 99%, Abcr § Tris (dimetilamino) arsina 99%, Abcr § Dibromobutano 99% ,Sigma-Aldrich § Ioduro de metilo 99%, Sigma-Aldrich § Ioduro de etilo 99%, Sigma-Aldrich § Acetonitrilo anhidro 99.9%, Sigma-Aldrich § Diclorometano anhidro 99.9%, Sigma-Aldrich § Tetrahidrofurano anhidro sin agente inhibidor >99.99%, Sigma-Aldrich Capítulo 3: Procedimiento Experimental 28 § Éter dietílico 99.5%, Sigma-Aldrich § Sulfato de magnesio 99,9%, Scharlab § Resina de intercambio iónico Amberlite IRN-78, Supelco § H2O milliQ (Millipore) § Acetona for HPLC, >99.9%, Sigma-Aldrich § Tetraetilortosilicato (TEOS), > 98%, Merck. § Sílice coloidal (Ludox AS-40), 40% en H2O, Sigma-Aldrich § Ácido bórico (H3BO3), > 99.5%, Sigma-Aldrich § Óxido de germanio (GeO2), 99.998 %, Sigma-Aldrich § Óxido de aluminio (Al2O3), 75%, Sigma-Aldrich § Nitrato de galio (Ga(NO3)3), 99.9%, Sigma-Aldrich § Ácido fluorhídrico (HF) 48%, Sigma-Aldrich § Fluoruro amónico >99.99%, Sigma-Aldrich § Disolución estándar de ácido clorhídrico (HCl), 0.1 N en H2O, Sigma-Aldrich
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