Abstract. Browning of inland waters has been noted over large parts of the Northern hemisphere and is a phenomenon with both ecological and societal consequences. The increase in water color is generally ascribed to increasing concentrations of dissolved organic matter of terrestrial origin. However, oftentimes the increase in water color is larger than that of organic matter, implying that changes in the concentration of organic matter alone cannot explain the enhanced water color. Water color is known to be affected also by the quality of organic matter and the prevalence of iron. Here we investigated trends in water color, organic matter and iron between 1972 and 2010 in 30 rivers draining into the Swedish coast (data from the national Swedish monitoring program), and performed a laboratory iron addition experiment to natural waters, to evaluate the role of iron and organic matter in determining water color. By comparing the effect of iron additions on water color in the experiment, to variation in water color and iron concentration in the monitoring data, we show that iron can explain a significant share of the variation in water color (on average 25 %), especially in the rivers in the north of Sweden (up to 74 %). Furthermore, positive trends for iron are seen in 27 of 30 rivers (21-468 %) and the increase in iron is larger than that of organic matter, indicating that iron and organic matter concentrations are controlled by similar but not identical processes. We speculate that increasing iron concentrations can be caused by changes in redox conditions, that mean that more anoxic water with high concentrations of soluble FeII are feeding into the surface waters. More studies are needed about why iron is increasing so strongly, since both causes and consequences are partly different from those of increasing organic matter content.
The aim of this study was to explore how acid deposition may affect the concentration and quality of dissolved organic matter (DOM) in soil-water. This was done by a small-scale acidification experiment during two years where 0.5 × 0.5 m(2) plots were artificially irrigated with water with different sulfuric acid content, and soil-water was sampled using zero-tension lysimeters under the O-horizon. The DOM was characterized using absorbance, fluorescence, and size exclusion chromatography analyses. Our results showed lower mobility of DOM in the high acid treatment. At the same time, there was a significant change in the DOM quality. Soil-water in the high acid treatment exhibited DOM that was less colored, less hydrophobic, less aromatic, and of lower molecular weight, compared to the low acid treatment. This supports the hypothesis that reduction in sulfur deposition is an important driver behind the ongoing brownification of surface waters in many regions.
Browning of inland waters has been noted over large parts of the Northern Hemisphere and is a phenomenon with both ecological and societal consequences. The increase in water color is generally ascribed to increasing amounts of dissolved organic matter of terrestrial origin. However, oftentimes the increase in water color is larger than that of organic matter, implying that changes in the amount of organic matter alone cannot explain the enhanced water color. Water color is known to be affected also by the quality of organic matter and the prevalence of iron. Here we investigated trends in water color, organic matter and iron between 1972 and 2010 in 30 rivers draining into the Swedish cost, and peformed a laboratory iron addition experiment to natural waters, to evaluate the role of iron and organic matter in determining water color. By comparing the effect of iron additions on water color in the experiment, to variation in water color and iron concentration in the monitoring data, we show that iron can explain a significant share of the variation in water color (on average 25%), especially in the rivers in the north of Sweden (up to 74%). Further more, positive trends for iron are seen in 27 of 30 rivers (21–468%) and the increase in iron is larger than that of organic matter, indicating that iron and organic matter concentrations are controlled by similar but not identical processes. We speculate that increasing iron concentrations can be caused by changes in redox conditions, that mean that more anoxic water with high concentrations of soluble FeII are feeding into the surface waters. More studies are needed about why iron is increasing so strongly, since both causes and consequences are partly different from those of increasing organic matter content
Recent studies report trends of strongly increasing iron (Fe) concentrations in freshwaters. Since Fe is a key element with a decisive role in the biogeochemical cycling of major elements, it is important to understand the mechanisms behind these trends. We hypothesized that variations in Fe concentration are driven mainly by redox dynamics in hydraulically connected soils. Notably, Fe(III), which is the favored oxidation state except in environments where microbial activity provide strong reducing intensity, has several orders of magnitude lower water solubility than Fe(II). To test our hypothesis, seasonal variation in water chemistry, discharge, and air temperature was studied in three Swedish rivers. Methylmercury and sulfate were used as indicators of seasonal redox changes. Seasonal variability in water chemistry, discharge, and air temperature in the Emån and Lyckeby Rivers implied that the variation in Fe was primarily driven by the prevalence of reducing conditions in the catchment. In general, high Fe concentrations were observed when methylmercury was high and sulfate was low, indicative of reducing conditions. The Fe concentrations showed no or weak relationships with variations in dissolved organic matter concentration and aromaticity. The seasonal variation in Fe concentration of the Ume river was primarily dependent on timing of the snowmelt in high‐ versus low‐altitude areas of the catchment. There were long‐term trends of increasing temperature in all catchments and also trends of increasing discharge in the southern rivers, which should increase the probability for anaerobic conditions in space and time and thereby increase Fe transport to the aquatic systems.
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