A memory device that can be switched between the normal state and superconducting state by an external magnetic field is proposed. The device consists of a superconducting/double magnetic (SM 1 M 2) trilayer and is switched in a manner analogous to giant magnetoresistive memory devices. Using Usadel equations it is shown that the superconducting transition temperature of the device changes when the magnetic configurations of magnetizations of the two lower layers are switched between parallel and antiparallel. Appropriate design parameters are discussed and the materials issues analyzed.
Single-crystal metals have distinctive properties owing to the absence of grain boundaries and strong anisotropy. Commercial single-crystal metals are usually synthesized by bulk crystal growth or by deposition of thin films onto substrates, and they are expensive and small. We prepared extremely large single-crystal metal foils by “contact-free annealing” from commercial polycrystalline foils. The colossal grain growth (up to 32 square centimeters) is achieved by minimizing contact stresses, resulting in a preferred in-plane and out-of-plane crystal orientation, and is driven by surface energy minimization during the rotation of the crystal lattice followed by “consumption” of neighboring grains. Industrial-scale production of single-crystal metal foils is possible as a result of this discovery.
Through-chip electrodes with high aspect ratios can offer the shortest interconnection and reduce signal delay. Copper has been selected as that electrode material because of its good compatibility to conventional multilayer interconnection in large-scale integration and back end-of-line processes. In this paper, filling vias with higher aspect ratio, 10 m 2 and 70 m depth, used for through-chip electrodes is reported. Removing overhang at via tops is important to achieve perfect via filling. Upon testing a series of electrodeposition conditions, conformal electrodeposits were obtained. With those conformal electrodeposits, seams and voids always remained at the via center. Perfect via filling was achieved by the pulse reverse plating method and by increasing Janus Green B concentration up to 20 mg/L in the plating bath.
Increasing dissipation-free supercurrent has been the primary issue for practical application of superconducting wires. For magnesium diboride, MgB 2 , carbon is known to be the most effective dopant to enhance high-field properties. However, the critical role of carbon remains elusive, and also low-field critical current density has not been improved. Here, we have undertaken malic acid doping of MgB 2 and find that the microscopic origin for the enhancement of high-field properties is due to boron vacancies and associated stacking faults, as observed by high-resolution transmission electron microscopy and electron energy loss spectroscopy. The carbon from the malic acid almost uniformly encapsulates boron, preventing boron agglomeration and reducing porosity, as observed by three-dimensional X-ray tomography. The critical current density either exceeds or matches that of niobium titanium at 4.2 K. Our findings provide atomic-level insights, which could pave the way to further enhancement of the critical current density of MgB 2 up to the theoretical limit.
Carbon‐encapsulated crystalline boron nanopowder and coarse magnesium powder are used as inexpensive tailored starting materials for the fabrication of high‐performance MgB2 superconducting wire. A low sintering temperature leads to a high critical current density, as a result of nanometer‐sized boron powder, surface oxidation preclusion by carbon encapsulation, and grain alignment by elongated magnesium coarse powder.
Aqueous-processed all-polymer solar cells (aq-APSCs) are reported for the first time by developing a series of water/ethanol-soluble naphthalenediimide (NDI)-based polymer acceptors [P(NDIDEG-T), P(NDITEG-T), and P(NDITEG-T2)]. Polymer acceptors are designed by using the backbones of NDI-bithiophene and NDI-thiophene in combination with nonionic hydrophilic oligoethylene glycol (OEG) side chains that facilitate processability in water/ ethanol mixtures. All three polymers exhibit sufficient solubility (20−50 mg mL −1 ) in the aqueous medium. The P(NDIDEG-T) polymer with shorter OEG side chains is the most crystalline with the highest electron mobility, enabling the fabrication of efficient aq-APSCs with the maximum power conversion efficiency (PCE) of 2.15%. Furthermore, these aq-APSCs are fabricated under ambient atmosphere by taking advantage of the eco-friendly aqueous process and, importantly, the devices exhibit outstanding air-stability without any encapsulation, as evident by maintaining more than 90% of the initial PCE in the air after 4 days. According to a double cantilever beam test, the interfacial adhesion properties between the active layer and electron/hole transporting layers were remarkably improved by incorporating the hydrophilic OEG-attached photoactive layer, which hinders the delamination of the constituent layers and prevents the increase of series resistance, ultimately leading to enhanced durability under ambient conditions. The combination of increased device stability and minimal environmental impact of these aq-APSCs demonstrates them to be worthy candidates for continued development of scalable polymer solar cells.
We study the transition temperature Tc, the thermodynamic critical field Bc, and the upper critical field Bc2 of Nb3Sn with Eliashberg theory of strongly coupled superconductors using the Einstein spectrum α2(ω)F(ω)=λ⟨ω2⟩1∕2δ(ω−⟨ω2⟩1∕2). The strain dependences of λ(ε) and ⟨ω2⟩1∕2(ε) are introduced from the empirical strain dependence of Tc(ε) for three model cases. It is found that the empirical relation Tc(ε)∕Tc(0)=[Bc2(4.2K,ε)∕Bc2(4.2K,0)]1∕w (w≈3) is mainly due to the low-energy-phonon mode softening. We derive analytic expressions for the strain and temperature dependences of Bc(T,ε) and Bc2(T,ε) and the Ginzburg-Landau parameter κ(T,ε) from the numerical calculation results. The Summers refinement on the temperature dependence of κ(T) shows deviation from our calculation results. We propose a unified scaling law of flux pinning in Nb3Sn strands in the form of the Kramer model with the analytic expressions of Bc2(T,ε) and κ(T,ε) derived in this work. It is shown that the proposed scaling law gives a reasonable fit to the reported data with only eight fitting parameters.
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