Previous studies reported that the drying time of a respiratory droplet on an impermeable surface along with a residual film left on it is correlated with the coronavirus survival time. Notably, earlier virus titer measurements revealed that the survival time is surprisingly less on porous surfaces such as paper and cloth than that on impermeable surfaces. Previous studies could not capture this distinct aspect of the porous media. We demonstrate how the mass loss of a respiratory droplet and the evaporation mechanism of a thin liquid film are modified for the porous media, which leads to a faster decay of the coronavirus on such media. While diffusion-limited evaporation governs the mass loss from the bulk droplet for the impermeable surface, a much faster capillary imbibition process dominates the mass loss for the porous material. After the bulk droplet vanishes, a thin liquid film remaining on the exposed solid area serves as a medium for the virus survival. However, the thin film evaporates much faster on porous surfaces than on impermeable surfaces. The aforesaid faster film evaporation is attributed to droplet spreading due to the capillary action between the contact line and fibers present on the porous surface and the modified effective wetted area due to the voids of porous materials, which leads to an enhanced disjoining pressure within the film, thereby accelerating the film evaporation. Therefore, the porous materials are less susceptible to virus survival. The findings have been compared with the previous virus titer measurements.

The present study experimentally and numerically investigates the evaporation and resultant patterns of dried deposits of aqueous colloidal sessile droplets when the droplets are initially elevated to a high temperature before being placed on a substrate held at ambient temperature. The system is then released for natural evaporation without applying any external perturbation. Infrared thermography and optical profilometry are used as essential tools for interfacial temperature measurements and quantification of coffee-ring dimensions, respectively. Initially, a significant temperature gradient exists along the liquid–gas interface as soon as the droplet is deposited on the substrate, which triggers a Marangoni stress-induced recirculation flow directed from the top of the droplet toward the contact line along the liquid–gas interface. Thus, the flow is in the reverse direction to that seen in the conventional substrate heating case. Interestingly, this temperature gradient decays rapidly within the first 10% of the total evaporation time and the droplet–substrate system reaches thermal equilibrium with ambient thereafter. Despite the fast decay of the temperature gradient, the coffee-ring dimensions significantly diminish, leading to an inner deposit. A reduction of 50–70% in the coffee-ring dimensions is recorded by elevating the initial droplet temperature from 25 to 75 °C for suspended particle concentration varying between 0.05 and 1.0% v/v. This suppression of the coffee-ring effect is attributed to the fact that the initial Marangoni stress-induced recirculation flow continues until the last stage of evaporation, even after the interfacial temperature gradient vanishes. This is essentially a consequence of liquid inertia. Finally, a finite-element-based two-dimensional modeling in axisymmetric geometry is found to capture the measurements with reasonable fidelity and the hypothesis considered in the present study corroborates well with a first approximation qualitative scaling analysis. Overall, together with a new experimental condition, the present investigation discloses a distinct nature of Marangoni stress-induced flow in a drying droplet and its role in influencing the associated colloidal deposits, which was not explored previously. The insights gained from this study are useful to advance technical applications such as spray cooling, inkjet printing, bioassays, etc.

We present the effect of 0.5 keV Ar + beam irradiation on the wetting properties of metallic thin films. Observations reveal a transition from hydrophilic to hydrophobic nature at higher beam fluences which can be attributed to a reduction in net surface free energy. In this lowenergy regime, ion beams do not induce significant surface roughness and chemical heterogeneity. However, they cause implantation of atomic impurities in the near surface region of the target and thus form a heterogeneous system at atomic length scales. Interestingly, the presence of implanted Ar atoms in the near surface region modifies the dispersive intermolecular interaction near the surface but induces no chemical modification due to their inert nature. On this basis, we have developed a theoretical model consistent with the experimental observations that reproduces the effective Hamaker constant with a reasonable accuracy.

We experimentally and theoretically investigate a distinct problem of spreading, evaporation, and the associated dried deposits of a colloidal particle-laden aqueous sessile droplet on a surface in a saturated alcohol vapor environment. In particular, the effect of particle size on monodispersed suspensions and efficient self-sorting of bidispersed particles have been investigated. The alcohol vapor diffuses toward the droplet's curved liquid−vapor interface from the far field. The incoming vapor mass flux profile assumes a nonuniform pattern across the interface. The alcohol vapor molecules are adsorbed at the liquid−vapor interface, which eventually leads to absorption into the droplet's liquid phase due to the miscibility. This phenomenon triggers a liquid−vapor interfacial tension gradient and causes a reduction in the global surface tension of the droplet. This results in a solutal Marangoni flow recirculation and spontaneous droplet spreading. The interplay between these phenomena gives rise to a complex internal fluid flow within the droplet, resulting in a significantly modified and strongly particle-size-dependent dried colloidal deposit. While the smaller particles form a multiple ring pattern, larger particles form a single ring, and additional "patchwise" deposits emerge. High-speed visualization of the internal liquid-flow revealed that initially, a ring forms at the first location of the contact line. Concurrently, the Marangoni flow recirculation drives a collection of particles at the liquid−vapor interface to form clusters. Thereafter, as the droplet spreads, the smaller particles in the cluster exhibit a "jetlike" outward flow, forming multiple ring patterns. In contrast, the larger particles tend to coalesce together in the cluster, forming the "patchwise" deposits. The widely different response of the different-sized particles to the internal fluid flow enables an efficient sorting of the smaller particles at the contact line from bidispersed suspensions. We corroborate the measurements with theoretical and numerical models wherever possible.

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