Solid-state flexible energy storage devices hold the key to realizing portable and flexible electronic devices. Achieving fully flexible energy storage devices requires that all of the essential components (i.e., electrodes, separator, and electrolyte) with specific electrochemical and interfacial properties are integrated into a single solid-state and mechanically flexible unit. In this study, we describe the fabrication of solid-state flexible asymmetric supercapacitors based on an ionic liquid functionalized-chemically modified graphene (IL-CMG) film (as the negative electrode) and a hydrous RuO(2)-IL-CMG composite film (as the positive electrode), separated with polyvinyl alcohol-H(2)SO(4) electrolyte. The highly ordered macroscopic layer structures of these films arising through direct flow self-assembly make them simultaneously excellent electrical conductors and mechanical supports, allowing them to serve as flexible electrodes and current collectors in supercapacitor devices. Our asymmetric supercapacitors have been optimized with a maximum cell voltage up to 1.8 V and deliver a high energy density (19.7 W h kg(-1)) and power density (6.8 kW g(-1)), higher than those of symmetric supercapacitors based on IL-CMG films. They can operate even under an extremely high rate of 10 A g(-1) with 79.4% retention of specific capacitance. Their superior flexibility and cycling stability are evident in their good performance stability over 2000 cycles under harsh mechanical conditions including twisted and bent states. These solid-state flexible asymmetric supercapacitors with their simple cell configuration could offer new design and fabrication opportunities for flexible energy storage devices that can combine high energy and power densities, high rate capability, and long-term cycling stability.

We report an approach that extends the applicability of ultrasensitive force-gradient detection of magnetic resonance to samples with spin-lattice relaxation times (T 1 ) as short as a single cantilever period. To demonstrate the generality of the approach, which relies on detecting either cantilever frequency or phase, we used it to detect electron spin resonance from a T 1 = 1 ms nitroxide spin probe in a thin film at 4.2 K and 0.6 T. By using a custom-fabricated cantilever with a 4 μm-diameter nickel tip, we achieve a magnetic resonance sensitivity of 400 Bohr magnetons in a 1 Hz bandwidth. A theory is presented that quantitatively predicts both the lineshape and the magnitude of the observed cantilever frequency shift as a function of field and cantilever-sample separation. Good agreement was found between nitroxide T 1 's measured mechanically and inductively, indicating that the cantilever magnet is not an appreciable source of spin-lattice relaxation here. We suggest that the new approach has a number of advantages that make it well suited to push magnetic resonance detection and imaging of nitroxide spin labels in an individual macromolecule to single-spin sensitivity.MRFM | ESR | TEMPAMINE | mechanically detected magnetic resonance | molecular structure imaging A generally applicable approach for determining the tertiary structure of an individual macromolecule in vitro at angstrom or subangstrom resolution would create exciting opportunities for answering many longstanding questions in molecular biology. For macromolecules too large to characterize by NMR or X-ray diffraction, the tertiary structure of proteins (1-3), nucleic acids (4, 5), and biomolecular assemblies (6, 7) can be explored by using inductively-detected electron spin resonance (ESR) to measure distances between pairs of attached spin labels (2-5, 7, 8). These studies, however, require bulk quantities of sample (9) and demand multiple experiments with spin labels attached to different locations in the target macromolecule. Mechanical detection and imaging of single-electron spins has been demonstrated, in E centers in gamma-irradiated quartz (10), and it is natural to explore applying magnetic resonance force microscopy (MRFM) (11-15) to map the locations of individual spin labels attached to a single biomacromolecule.The ultimate limit of imaging resolution in MRFM is set by the intrinsic linewidth of the resonance and the applied magnetic field gradient. For a 0.1 mT homogeneous linewidth, typical of the organic radical studied here, a gradient of 4 × 10 6 T/m allows selective excitation of individual spin labels only 0.025 nm apart. A magnetic field gradient this large has recently been demonstrated in an MRFM experiment by using ferromagnetic pillars fabricated by electron-beam lithography (15). The force sensitivity required to detect single electrons in this gradient is 40 aN, above the minimum detectable force (in 1 Hz bandwidth) of 5 − 10 aN reported for a high-compliance cantilever operated with its metalized leading edge above ...

We have batch-fabricated cantilevers with ~100 nm diameter nickel nanorod tips and force sensitivities of a few attonewtons at 4.2 kelvin. The magnetic nanorods were engineered to overhang the leading edge of the cantilever and, consequently, the cantilevers experience what we believe is the lowest surface noise ever achieved in a scanned probe experiment. Cantilever magnetometry indicated that the tips were well magnetized, with a ≤ 20 nm dead layer; the composition of the dead layer was studied by electron microscopy and electron energy loss spectroscopy. In what we believe is the first demonstration of scanned probe detection of electron-spin resonance from a batch fabricated tip, the cantilevers were used to observe electron-spin resonance from nitroxide spin labels in a film via force-gradient-induced shifts in cantilever resonance frequency. The magnetic field dependence of the magnetic resonance signal suggests a non-uniform tip magnetization at an applied field near 0.6 T.

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This paper presents a design of a 35 T 40 mm winding diameter no-insulation standalone magnet that consists of a stack of 52 double pancake (DP) coils wound with multi-width REBCO tapes. The inner and outer diameters and height of the magnet are 40 mm, 221.6 mm, and 628 mm, respectively. It is designed to generate 35 T at an operating current (Iop) of 179.8 A in a bath of liquid helium at 4.2 K. All the DP coils will be ‘dry’ wound without epoxy, making turns within the DP coils to be essentially ‘self-supporting,’ which is effective to reduce the magnetic stress. To reduce the magnet charging time constant, the so-called ‘metallic cladding’ REBCO tapes will be adopted, where a 1–2 μm thick stainless steel layer surrounds the tapes hermetically. With an average surface contact resistance (Rct) of 170 cm−2, experimentally obtained from a charging test of our recent 3 T 100 mm stainless steel cladding REBCO magnet, the charging time constant of the 35 T magnet was estimated to be 3.01 minutes, though the magnet will be energized substantially slower over a few hours to reduce ac loss and Joule heating from radial turn-to-turn leak currents. A preliminary post-quench analysis, based on our lumped equivalent circuit model, was performed; the total stored energy of 1.79 MJ (magnet inductance: 110.5 H) was expected to be discharged in approximately 1.28 seconds after a quench due to the fast electromagnetic quench propagation among the DP coils, while the peak hot spot temperature was estimated to rise to 94 K, acceptable for a safe quench of a REBCO magnet.