We prepared metallic-nanoparticle-embedded one-dimensional titanium dioxide (1D-TiO 2 ) via a one-step electrospinning process, in which Au or Ag metallic nanoparticles between 5 and 10 nm in diameter were incorporated within the TiO 2 nanofibers. After calcination of the composite nanofibers at high temperature of 450 °C, the nanofibers were converted to 1D-TiO 2 by the thermal decomposition of polyvinylpyrrolidone (PVP). This process simultaneously changed the metal precursors (AgNO 3 or HAuCl 4 • 3H 2 O) to metallic nanoparticles (Ag or Au) to produce 1D-TiO 2 nanofiber composites
We report a novel architecture of SnO(2) nanorod-planted graphite particles for an efficient Li ion storage material that can be prepared by a simple catalyst-assisted hydrothermal process. Rectangular-shaped SnO(2) nanorods are highly crystalline with a tetragonal rutile phase and distributed uniformly over the surface of micrometer-sized graphite particles. In addition, the size dimensions of grown SnO(2) nanorods can be controlled by varying the synthesis conditions. The diameter can be engineered to a sub-100 nm range, and the length can be controlled to up to several hundred nanometers. Significantly, the SnO(2) nanorod-planted graphite demonstrates an initial Li ion storage capacity of about 1010 mAh g(-1) during the first cycle. Also, these SnO(2)-graphite composites show high Coulombic efficiency and cycle stability in comparison with SnO(2) nanomaterials that are not combined with graphite. The enhanced electrochemical properties of SnO(2) nanorod-planted graphite, as compared with bare SnO(2) materials, inspire better design of composite materials with effective nanostructural configurations for advanced electrodes in lithium ion batteries.
We report here a simple and easy method of fabricating arranged inorganic nanowire architecture via electrospinning method equipped with a devised collector and demonstrate hybrid photovoltaic cells that are fashioned of planar-aligned TiO2 nanowire architectures such as uniaxially aligned nanowires and multiple layers of cross-aligned nanowire arrays with poly[2-methoxy, 5-(2′-ethyl-hexyloxy)-1,4-phenylenevinylene]. The power conversion efficiency can be significantly improved by at least 70% under 1sun condition depending on the degree of aligning TiO2 nanowire arrays through enhancing charge collection and transport rate, as well as facilitating the polymer infiltration as compared to a randomly collected TiO2 nanowire electrode.
The Pohang Light Source (PLS) has operated for 14 years successfully. To meet the request of the increasing user community, the PLS-II that is the upgrade project of PLS has been completed. Main goals of the PLS-II are to increase beam energy to 3 GeV, to increase number of insertion devices by the factor of two (20 IDs), to increase beam current to 400 mA and to reduce beam emittance below 10 nm with existing PLS tunnel and injection system. The PLS-II had been commissioned over the six months. During commissioning, we achieved 14 insertion devices operation and top-up operation with 100 mA beam current and 5.8 nm beam emittance. In this paper, we report the experimental results from the PLS-II commissioning.
Here, we report Si pillar and well arrays as tailored electrode materials for advanced Li ion storage devices. The well-ordered and periodic morphologies were formed on a Si electrode thin film via laser interference lithography followed by a dry etch process. Two different patterns of negatively or positively carved Si electrodes exhibited highly improved cycle performance as a consequence of the enlarged surface area and the nanoscale pattern effects. The Si well arrays showed the highest energy density, rate capability, and cycling retention among the prepared Si electrodes. This tailored electrode platform demonstrates that these design principles could be applied to future developments in Si electrodes.
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