Radio interferometry techniques are often used to investigate shock and detonation phenomena thanks to the radio‐transparency of high explosives in the gigahertz frequency band. These techniques require the knowledge of the permittivity of studied explosives. Although the permittivity has been thoroughly studied for many materials, very few data are available at high frequencies (>75 GHz) for high explosives. In this paper, we report static measurement data of the permittivity for various reactive materials using the standard line transmission method between 75 GHz and 110 GHz (W frequency Band), and we present dynamic measurement results at 94 GHz obtained from the so‐called detonation wavefront tracking method. It is shown that the measurement results provided by these two methods are in good agreement. As a consequence, this work validates the detonation wavefront tracking method for the dynamic measurement of high explosives permittivity, and shows that the static experimental results are relevant for shock wave propagation analysis from millimeter‐wave measurement techniques.

A thermochemical code, SIAME, dedicated to the study of high explosives, is currently being validated. From this code, both the parameters of the JWL equation of state of a given composition are calibrated from the calculated adiabatic curve and tabulated equations of state are constructed. SIAME code uses BKW equations with a specific calibration presented in this study. Calculated adiabatic curves are compared with the one obtained with the American code CHEETAH with the BKWC, BKWS and EXP6 calibrations for two different high explosive formulations: a melt-cast one (RDX/TNT 60/40 % wt.) and a pressed one (HMX/ Viton 96/4 % wt.). The validity of the constant entropy curves obtained with the JWL EOS and the tabulated EOS is investigated from the Chapman-Jouguet state to several dozens of megapascals to cover all the high explosive effects. Experimental results obtained for the two high explosives with the cylinder test and the impedance matching test are presented in this study and offer a set of validation points.