In this work an innovative electrospinning system is proposed that simultaneously has an adequate temperature resistance, a high increase in mode I (þ51%) and mode II (þ96%) delamination performance and can be commercially produced. Interleaving nanofibrous veils can potentially solve the issue of the limited delamination resistance encountered in composite laminates, but industrial upscaling has always been impeded by one or more critical factors. These constraining factors include a limited temperature stability of the nanofibers, a lack in simultaneous mode I and II delamination performance increase and the complexity of the electrospinning system because non-commercial polymers or specialty nanofibers (e.g. coaxial) are required. In this paper, a robust electrospinning system is proposed that is the first to overcome all major hurdles to make nanofiber toughening industrially viable. A new class of nanofibers based on biosourced polyamide 11 and its poly(ether-block-amide) co-polymers is used to deal with those shortcomings. The nanofibers have tuneable diameters down to 50 nm and cross-section morphologies ranging from circular to ribbon-shaped. The key to this work is the fundamental underpinning of the toughening effect using a broad range of interleaves with different mechanical and thermal properties, fiber diameters and fiber morphologies, all produced from the same bio-based base polymer. Generally, round and thin nanofibers performed better than larger and ribbon-like fibers. The relationship between the fiber morphology and the delamination performance is further underpinned using detailed analysis of the fracture surface. Ultimately, this results in a range of optimized nanofibrous veils capable of improving the delamination resistance considerably without suffering from the aforementioned drawbacks.
Recent development in the field of additive manufacturing, also known as three-dimensional (3D) printing, has allowed for the incorporation of continuous fiber reinforcement into 3D-printed polymer parts. These fiber reinforcements allow for the improvement of the mechanical properties, but compared to traditionally produced composite materials, the fiber volume fraction often remains low. This study aims to evaluate the in-nozzle impregnation of continuous aramid fiber reinforcement with glycol-modified polyethylene terephthalate (PETG) using a modified, low-cost, tabletop 3D printer. We analyze how dimensional printing parameters such as layer height and line width affect the fiber volume fraction and fiber dispersion in printed composites. By varying these parameters, unidirectional specimens are printed that have an inner structure going from an array-like to a continuous layered-like structure with fiber loading between 20 and 45 vol%. The inner structure was analyzed by optical microscopy and Computed Tomography (µCT), achieving new insights into the structural composition of printed composites. The printed composites show good fiber alignment and the tensile modulus in the fiber direction increased from 2.2 GPa (non-reinforced) to 33 GPa (45 vol%), while the flexural modulus in the fiber direction increased from 1.6 GPa (non-reinforced) to 27 GPa (45 vol%). The continuous 3D reinforced specimens have quality and properties in the range of traditional composite materials produced by hand lay-up techniques, far exceeding the performance of typical bulk 3D-printed polymers. Hence, this technique has potential for the low-cost additive manufacturing of small, intricate parts with substantial mechanical performance, or parts of which only a small number is needed.
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