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An expeditious and modular CuAAC ‘click’ protocol has been exploited for the construction of porphyrin cored hybrid glycodendrimers of G1 and G2 generation. The developed porphyrin hybrid glycodendrimers were characterized using extensive spectral analysis including NMR (1H, 13C, and 19F), MS, MALDI‐TOF, IR, and SEC datas and evaluated for their sensing ability for a range of metal ions, where they displayed notable sensing for Cu(II) ion with solvatochromism properties.