Waste heat can be directly converted into electrical energy by performing the Olsen cycle on pyroelectric materials. The Olsen cycle consists of two isothermal and two isoelectric field processes in the electric displacement versus electric field diagram. This paper reports on the electrical energy generated by lanthanum-doped lead zirconate titanate (8/65/35 PLZT) subjected to the Olsen cycle. The material was alternately dipped into a cold and a hot silicone oil bath under specified electric fields. A maximum energy density of 888 J l −1 /cycle was obtained with a 290 µm thick 8/65/35 PLZT sample for temperatures between 25 and 160 • C and electric fields cycled between 0.2 and 7.5 MV m −1. To the best of our knowledge, this is the largest pyroelectric energy density experimentally measured with multiple cycles. It corresponded to a power density of 15.8 W l −1. The electrical breakdown strength and therefore the energy and power densities of the material increased as the sample thickness was reduced from 720 to 290 µm. Furthermore, a physical model for estimating the energy harvested by ferroelectric relaxors was further validated against experimental data for a wide range of electric fields and temperatures.
Thermal energy harvesting from Pb ( Zn 1 / 3 Nb 2 / 3 ) 0.955 Ti 0.045 O 3 single crystals phase transitions This paper demonstrates a new power cycle for direct conversion of mechanical energy into electrical energy under a thermal bias. The cycle consisted sequentially of (i) an electric poling process under zero stress, (ii) an isoelectric process consisting of applying a uniaxial compressive stress r H followed by (iii) an electric de-poling process under constant compressive stress, and finally (iv) an isoelectric process consisting of removing the compressive stress. The new cycle was performed at constant bias-temperature T b . It was demonstrated on [001]-poled 0.72PbMg 1=3 Nb 2=3 O 3 -0.28PbTiO 3 single crystals. The power density increased with increasing cycle frequency and compressive stress for frequency up to 1 Hz. Maximum energy and power densities of 44 J/l/cycle and 44 W/l were achieved at 1 Hz for bias-temperature T b of 80 C and electric field cycled between 0.2 and 0.8 MV/m with compressive stress r H ¼ 25.13 MPa. This was attributed to a tetragonal-monoclinic-orthorhombic phase transition sequence. The material efficiency reached up to 87% and exceeded that of a similar thermomechanical power cycle performed on pyroelectric material. Finally, a physical model predicting the power density was derived and yielded accurate predictions of experimental data for all biastemperatures considered and cycle frequency up to 1 Hz. V C 2013 AIP Publishing LLC.
This paper reports on direct thermal to electrical energy conversion by performing the Olsen cycle on 9.5/65/35 lead lanthanum zirconate titanate (PLZT). The Olsen cycle consists of two isothermal and two isoelectric field processes in the electric displacement versus electric field diagram. It was performed by alternatively dipping the material in hot and cold dielectric fluid baths under specified electric fields. The effects of applied electric field, sample thickness, electrode material, operating temperature, and cycle frequency on the energy and power densities were investigated. A maximum energy density of 637 ± 20 J/L/cycle was achieved at 0.054 Hz with a 250-μm-thick sample featuring Pt electrodes and coated with a silicone conformal coating. The operating temperatures varied between 3°C and 140°C and the electric field was cycled between 0.2 and 6.0 MV/m. A maximum power density of 55 ± 8 W/L was obtained at 0.125 Hz under the same operating temperatures and electric fields. The dielectric strength of the material, and therefore the energy and power densities generated, increased when the sample thickness decreased from 500 to 250 μm. Furthermore, the electrode material was found to have no significant effect on the energy and power densities for samples subject to the same operating temperatures and electric fields. However, samples with electrode material possessing thermal expansion coefficients similar to that of PLZT were capable of withstanding larger temperature swings. Finally, a fatigue test showed that the power generation gradually degraded when the sample was subject to repeated thermoelectrical loading.
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