L-Histidine immobilized montmorillonite is prepared and used as an adsorbent for removal of As(III) from aqueous solutions. The L-Histidine immobilized montmorillonite is characterized by FTIR, XRD, TGA and PZC techniques that confirmed the successful insertion of Histidine into interlayer of montmorillonite structure. The various parameters such as pH, reaction time, temperature, concentration of As(III) and adsorbent dosage are optimized to obtain maximum As(III) adsorption. It is observed that usually the removal of As(III) is increased with increasing the amount of adsorbent, contact time, temperature and till pH 6. The results showed that all these adsorption parameters greatly influenced the adsorption process. The various adsorption isotherm models including Langmuir, Freundlich, Temkin and Dubinin-Radishkevich (DR) as well as kinetics models are applied to the adsorption data. The Langmuir isotherm and pseudo-second order kinetics model are well-fitted to the adsorption data. Further, the probability distribution function (PDF) is applied that verified the adsorption data well while the Akaike’s Information Criterion (AICcorrected) and Absolute Average Relative Deviation (AARD) statistical models supported the best fit adsorption isotherms. The PDF model have provided a good statistical identification of adsorption parameters, adsorption rates and maxima whereas AICcorrected and AARD models revealed the well-fitting of Langmuir adsorption isotherm model in correlating the equilibrium data. Thermodynamic parameters (ΔH, ΔS, ΔG) proved the endothermic and spontaneous nature of adsorption process along with entropical changes occurring at solid-solution interface. The results showed that L-Histidine immobilized montmorillonite is an excellent material for As(III) adsorption with maximum adsorption capacity of 87.7 mg g−1.
Textile effluents constitute both organic and inorganic constituents and heavy metals which are not economical to treat and hence discharged into water bodies causing water pollution. Methods like ozonation, adsorption, membrane separation, bio sorption, biodegradation, electrochemical degradation, and phytoremediation and H2O2/UV radiation techniques were frequently used for the decolourization of azo dye containing water. Among these aforementioned techniques, the adsorption technique has shown good performance owing to several inherent advantages like high performance, easy handling with no generation of the toxic intermediates. Also dye treatment should be affordable and eco-friendly. Biochar is a sustainable material which can be used for dyes treatment. In this paper, biochar produced using coconut shell was investigated for the removal of methylene blue as the colouring agent. Batch studies were carried out for decolourization of methylene blue based artificial waste water. Different concentrations of methylene blue from 50-300mg/l was used. The validation of the tests was done using data to fit into the Langmuir isotherms and Freundlich isotherm. The adsorption isotherm was well fitted for Langmuir compared to Freundlich. The KL and KF values were also found.
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