The recovery of scandium (Sc) from wastes and various resources using solvent extraction (SX) was discussed in detail. Moreover, the metallurgical extractive procedures for Sc recovery were presented. Acidic and neutral organophosphorus (OPCs) extractants are the most extensively used in industrial activities, considering that they provide the highest extraction efficiency of any of the valuable components. Due to the chemical and physical similarities of the rare earth metals, the separation and purification processes of Sc are difficult tasks. Sc has also been extracted from acidic solutions using carboxylic acids, amines, and acidic β-diketone, among other solvents and chemicals. For improving the extraction efficiencies, the development of mixed extractants or synergistic systems for the SX of Sc has been carried out in recent years. Different operational parameters play an important role in the extraction process, such as the type of the aqueous phase and its acidity, the aqueous (A) to organic (O) and solid (S) to liquid (L) phase ratios, as well as the type of the diluents. Sc recovery is now implemented in industrial production using a combination of hydrometallurgical and pyrometallurgical techniques, such as ore pre-treatment, leaching, SX, precipitation, and calcination. The hydrometallurgical methods (acid leaching and SX) were effective for Sc recovery. Furthermore, the OPCs bis(2-ethylhexyl) phosphoric acid (D2EHPA/P204) and tributyl phosphate (TBP) showed interesting potential taking into consideration some co-extracted metals such as Fe(III) and Ti(IV).
The nanoparticles of the magnetic core-shell Fe3O4@SiO2 were produced using a modified Stöber approach and functionalized with (3-amino-propyl) APTES triethoxysilane and ethylene-diamine-tetra-acetic acid (EDTA). Magnetic nano adsorbents exhibit many attractive opportunities for different purposes due to their easy removal and possibility of reusing these nanoparticles. The ligands grafting was chemically stable and did not affect the morphology or substrate structure appreciably. APTES-EDTA microspheres were formed for the removal from aqueous solution solutions of trivalent rare earth elements ions since the REEs have a strong oxygen affinity. The advantages of the SiO2 shell that covers the magnetite nanoparticles include lower specific weight and a larger grafting density compared to other surfaces, improving the resistance to acidic environments. Different techniques have described the particle size, morphology, precise surface area and surface alteration including Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and vibrating sample magnetometer (VSM). The results show that the Fe3O4 nanoparticles with an average particle size of 15 ± 3 nm were successfully synthesized at pH=11, at 25 °C temperature. Moreover, The nanoparticles prepared for Fe3O4 were coated with amorphous SiO2 and functionalized with amino and carboxylic groups.
The aim of this study was to prepare novel supramolecular hybrid nanoparticles (HNPs) that can selectively separate and recover scandium metal ions, Sc(III), from an aqueous phase based on molecular recognition technology (MRT). Moreover, this approach is fully compatible with green chemistry principles. In this work, natural amorphous silica (SiO2) nanoparticles were prepared by a precipitation method from Iraqi rice husk (RH) followed by surface modification with 3-amino-propyl triethoxysilane (APTES) as coupling agent and Kryptofix 2.2.2 (K2.2.2) as polycyclic ligand. To evaluate the potential of the hybrid nanoparticles, the prepared HNPs were used for the solid–liquid extraction of scandium, Sc(III), ions from model solutions due to the fact that K2.2.2 are polycyclic molecules. These polycyclic molecules are able to encapsulate cations according to the corresponding cavity size with the ionic radius of metal by providing a higher protection due their cage-like structures. Moreover, the authors set the objectives to design a high-technology process using these HNPs and to develop a Sc recovery method from the aqueous model solution prior to employing it in industrial applications, e.g., for Sc recovery from red mud leachate. The concentrations of Sc model solutions were investigated using the UV-Vis spectrophotometer technique. Different characterization techniques were used including scanning electron microscope (SEM), atomic force microscopy (AFM), Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), X-ray fluorescence (XRF), and Fourier transform infrared (FTIR). The extraction efficiency of Sc varied from 81.3% to 96.7%. Moreover, the complexed Sc ions were efficiently recovered by HCl with 0.1 mol/L concentration. The stripping ratios of Sc obtained ranged from 93.1% to 97.8%.
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