Persulfate-based oxidation of recalcitrant pollutants has been investigated as an alternative to OH radical based advanced oxidation processes due to distinct merits such as greater stability and non-selective persistent reactivity of SO oxidant species. The present study has attempted to highlight mechanistic features of persulfate-based decolorization of textile dye (Azorubine) using sono-hybrid techniques of activation. Three activation techniques, viz. sonolysis, Fe ions and UVC light and combinations thereof, have been examined. UVC is revealed to be the most efficient decolorization technique. The mechanism of sonolysis (i.e. thermal activation of persulfate in the bubble-bulk interfacial region) is revealed to be almost independent of the mechanism of UVC. Fe activation is revealed to have an adverse interaction with UVC due to scavenging of sulfate radicals by Fe ions. The best hybrid activation technique for persulfate-based degradation and mineralization of Azorubine is UVC+ultrasound. Due to independent mechanisms, degradation and mineralization of the dye obtained with simultaneous application of UVC and ultrasound is nearly equal to the sum of degradation and mineralization obtained using individual techniques.
In recent times, the Li‐CO2 battery has gained significant importance arising from its higher gravimetric energy density (1876 Wh kg‐1) compared to the conventional Li‐ion batteries. Also, its ability to utilize the greenhouse gas CO2 to operate an energy storage system and the prospective utilization on extraterrestrial planets such as Mars motivate to practicalize it. However, it suffers from numerous challenges such as (i) the reluctant CO2 reduction/evolution; (ii) solid/liquid/gas interface blockage arising from the deposition of Li2CO3 discharge product on the cathode; (iii) high overpotential to decompose the stable discharge product Li2CO3; and (iv) instability of the electrolytes. Numerous efforts have been undertaken to tackle these challenges by developing catalysts, improving the stability of electrolytes, protecting the anode, etc. Despite these efforts, due to the lack of a decisive confirmation of the reaction mechanisms of the discharging/charging reactions occurring in the system, the progress of the Li–CO2 battery system has been slow. In situ characterization techniques help overcome ex‐situ techniques’ limitations by monitoring the processes with the progress of a reaction. The current review focuses on bridging the gap in the understanding of the Li–CO2 batteries by exploring the various in situ/operando characterization techniques that have been employed.
The last two decades have witnessed an exponential rise in web content from a plethora of domains, which has necessitated the use of domain-specific search engines. Diversity of crawled content is one of the crucial aspects of a domainspecific search engine. To a large extent, diversity is governed by the initial set of seed URLs. Most of the existing approaches rely on manual effort for seed selection. In this work we automate this process using URLs posted on Twitter. We propose an algorithm to get a set of diverse seed URLs from a Twitter URL graph. We compare the performance of our approach against the baseline zero similarity seed selection method and find that our approach beats the baseline by a significant margin.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.