Metallo adducts involving Cu(i), Ag(i) and Au(i) Lewis acids and iron and manganese centered organometallic Lewis bases have been investigated using phosphine and N-heterocyclic carbene supporting ligands.
Density functional theory calculations at the M06-D3/def2-TZVPPD level of the group-13 anion complexes EFe(CO)3- (E = B – Tl) and the isoelectronic neutral and charged boron adducts BTM(CO)3q (TMq =...
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