AB STRACT:This study aims to describe the application of water pinch technology in industrial water consumption management in aluminum anodizing industry. Water pinch analysis is a systematic technique for designing, optimization and retrofitting of energy, mass and water recovery networks. The selection of different operations existing in an industry has an important role in correctness of application of pinch technology. Water usages in anodizing industry are various, but researches have been shown that, it has the best efficiency on the selection of rinsing chambers to pinch technology. There are different methods in pinch technology mostly based on mass transfer of single or multiple contaminants. In this research, a new method is used to select effective contaminant to be applied to pinch analysis. This research is based on Mann and Liu's method in single contaminant. But "the guide for classification of raw water, wastewater and recycled water for industrial and recreation" is chosen to use a complex of index contaminants as a single contaminant. This method is very simple and applicable for various industrial processes. By an index contaminant like total dissolved solids, the water usage reduced about 6.7 %. Using pinch technology and this new approach in three rinsing chambers, water usage reduced about 14.4 %.
Almost 2555-4380 tons of paint sludge are produced annually in an auto-manufacturing plant; recycling and reproduction of beneficial materials such as titanium dioxide (TiO2) and its application in paint production from paint sludge are evaluated in this article. The disposal of these sludge is environmentally important and is the main and most serious challenge for auto-manufacturing units. Today, these sludge are recognized as toxic wastes, whose disposal is much costly and constrained by environmental standards. Controlled disposal requires spaces, which are expensive and impermeable, because the sludge contains large amounts of hazardous materials such as heavy metals, solvents, and other materials polluting wells, springs, and other water resources. In this research, X-ray diffraction spectroscopy was carried out to determine the types of sludge combinations. Then, chemical digestion and centrifuge was used to extract TiO2, the extracted TiO2 reached 67.41% using these techniques. Next, a powder containing TiO2 in a certain percentage was used for paint production. Here, not only the amount of sludge decreased to as much as 70% but also the fresh paint required annually will be reduced by 21%. Furthermore, all heavy metals and toxic wastes will be removed as an environmental challenge.
This study was undertaken to investigate the removal of Acid Orange 2 (sodium 4-[(2E)-2-(2-oxonaphthalen-1-ylidene) hydrazinyl] benzenesulfonate) and Reactive Blue 19 (2-Anthracenesulfonicacid,1-amino-9,10-dihydro-9,10-dioxo-4-[[3-[[2-(sulfooxy) ethyl] sulfonyl] phenyl] amino]-,sodium salt (1:2)) from synthesized and real effluents through electrocoagulation using solar cells for the purpose of improving economic efficiency of the process. The impact of a number of key operating parameters was explored including current density, anode type, temperature, pH, and electrolyte concentration. The current density of 45 Am(-2) proved to be the optimum level for both dyes. The same optimum alternatives were found for the other parameters in both cases: iron anode, a temperature level of 25°C, a pH of 7, and an electrolyte concentration of 15 mg L(-1). Both effluent samples were subjected to COD (chemical oxygen demand) and TOC (total organic carbon) tests. Cost analysis was performed for the treatment process.
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