YbVO nanostructure and YbVO/CuWO nanocomposites were successfully synthesized using sonochemical method, for the first time. In this disquisition, we tried to compare various parameters and reaction conditions on size, morphology, and uniformity of as-obtained samples. To reach optimum condition, some parameters including time, power, temperature, and solvent were investigated. The structural, morphological, optical, and magnetic properties of as-obtained products were characterized by some techniques such as FT-IR, XRD, EDS, SEM, TEM, UV-Vis, and VSM. Furthermore, due to occurrence of red shift in nonanocomposite, during the coupling of CuWO into YbVO, photocatalytic and optical properties of final products were improved which lead to improve photo-destruction efficiency for methylene blue from 65% to 100%, during 120 min irradiation. The effect of the ultrasonic radiation on the photocatalytic behavior of YbVO/CuWO shows that methylene blue pollutant destruction was about 100% with ultrasonic wave and 61% in the absence of ultrasonic radiation.
Fe3O4/CdWO4 and Fe3O4/CdWO4/PrVO4 magnetic nanoparticles were prepared at different molar ratios of PrVO4 to previous layers (Fe3O4/CdWO4) via the co-precipitation method assisted by a sonochemical procedure, in order to investigate the photocatalytic performance of these systems and their cytotoxicity properties. The physico-chemical properties of these magnetic nanoparticles were determined via several experimental methods: X-ray diffraction, energy dispersive X-ray spectroscopy, Fourier transformation infrared spectroscopy and ultraviolet-visible diffuse reflection spectroscopy, using a vibrating sample magnetometer and a scanning electron microscope. The average sizes of these nanoparticles were found to be in the range of 60–100 nm. The photocatalytic efficiency of the prepared nanostructures was measured by methylene blue degradation under visible light (assisted by H2O2). The magnetic nanosystem with a 1:2:1 ratio of three oxide components showed the best performance by the degradation of ca. 70% after 120 min of exposure to visible light irradiation. Afterwards, this sample was used for the photodegradation of methyl orange, methyl violet, fenitrothion, and rhodamine-B pollutants. Finally, the mechanism of the photocatalytic reaction was examined by releasing •OH under UV light in a system including terephthalic acid, as well as O2−, OH, and hole scavengers. Additionally, the cytotoxicity of each synthesized sample was assessed using a 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay against the human cell line PANC1 (cancer), and its IC50 was approximately 125 mg/L.
Magnetic Fe3O4/ZnWO4 and Fe3O4/ZnWO4/CeVO4 nanoparticles with different molar ratios of CeVO4 to other inorganic components were synthesized through co-precipitation with a sonochemical-assisted method. X-ray diffraction, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, vibrating sample magnetometry, and scanning electron microscopy (SEM) methods were used for the physico–chemical characterization of the obtained nanoparticles. As shown in the SEM images, the average sizes of the Fe3O4/ZnWO4 and Fe3O4/ZnWO4/CeVO4 nanoparticles that formed aggregates were approximately 50–70 nm and 80–100 nm, respectively. The photocatalytic performance of these nanoparticles was examined by measuring methylene blue degradation under visible light (assisted by H2O2). The sample with a mass ratio of 1:2:1 (Fe3O4/ZnWO4/CeVO4, S4) exhibited optimal photocatalytic performance, and thus this sample was subsequently used for the photodegradation of different organic pollutants upon irradiation with ultraviolet (UV) and visible light. Approximately 90% and 70% degradation of methyl violet and methylene blue, respectively, was observed after visible light irradiation. Additionally, the mechanism of the photocatalytic reaction was investigated by measuring ˙OH release under UV light in a system with terephthalic acid and by measuring the release of ˙O2−, ˙OH, and hole scavengers.
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