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Strong interactions between mechanical deformation and chemical reactions may play a critical role in the response of geomaterials or geological systems to evolving environmental circumstances that may occur in both natural and engineered processes. The present study focuses on mineral dissolution and precipitation at the intergranular contact whose consequences are often manifested at the macro-scale where the mechanical and transport properties of the geomaterial may be altered. Discrete element modeling is employed to explore two applications involving such mineral transformations. The first example is primarily focused on the chemo-mechanical coupling mechanisms of intergranular contact in the natural process of pressure solution and secondary compression. The effect of the mineral dissolution on the mechanical response at the grain contact is incorporated into the contact model. Discrete element simulations are performed to examine the overall mechanical response of particle assembles subject to mineral dissolution and the results demonstrate the important role of the kinetic rate characteristics of the dissolution process. The second part of the present study revolves around the effect of mineral precipitation in an engineered process known as microbially induced calcite precipitation for potential soil improvement. The kinetics of involved bio-chemical process is incorporated into on the contact model and the simulation results indicate considerable strengthening effect. Overall, the present study demonstrates the feasibility of discrete element approach as a numerical tool to model coupled chemo-mechanical phenomena across the scales.

Evolution of the mechanical and hydraulic properties of geomaterials may be strongly influenced by the interaction of chemical and mechanical processes in various environmental circumstances. This paper presents a numerical study of the evolution of mechanical and transport properties enhanced by mineral dissolution across scales. Numerical models are developed at the discrete element level to involve the chemo-mechanical couplings and lead to the evaluation of material behavior at the macro-scale. Discrete element modeling of a biaxial test was performed to simulate the strain development enhanced by chemo-mechanical coupling effects. The results show the important role of the kinetic rate characteristics of the dissolution process in the behavior of geomaterials. The presented analysis demonstrates the effectiveness of DEM as a useful tool to model coupled chemo-mechanical phenomena.