Modification of nano‐WO3 with −SO3H groups as a covalently grafted solid acid reduced its band‐gap energy from 2.8 to 2.4 eV and made it an ideal nominee for photocatalytic reaction under visible light irradiation. This nano‐photocatalyst has been successfully used for the selective oxidation of different benzyl alcohols to corresponding aldehydes under blue LED irradiation. The reaction became approximately two times faster with excellent yields. It has shown that the nitrobenzene as an available industrial oxidant is applicable for photocatalytic oxidation of benzyl alcohol; remarkably high yield and selectivity have been observed.
Unfortunately, malaria still remains a major problem in tropical areas, and it takes thousands of lives each year and causes millions of infected cases. Besides, on December 2019, a new virus known as coronavirus appeared, that its rapid prevalence caused the World Health Organization (WHO) to consider it a pandemic. As a potential drug for controlling or treating these two undesired diseases at the cellular level, chloroquine and its derivatives are being investigated, although they possess side effects, which must be reduced for effective and safe treatments. With respect to the importance of this medicine, the current research aimed to calculate the solubility of chloroquine in supercritical carbon dioxide, and evaluated effect of pressure and temperature on the solubility. The pressure varied between 120 and 400 bar, and temperatures between 308 and 338 K were set for the measurements. The experimental results revealed that the solubility of chloroquine lies between 1.64 × 10
−5
to 8.92 × 10
−4
(mole fraction) with different functionality to temperature and pressure. Although the solubility was indicated to be strong function of pressure and temperature, the effect of temperature was more profound and complicated. A crossover pressure point was found in the solubility measurements, which indicated similar behaviour to an inflection point. For the pressures higher than the crossover point, the temperature indicated direct effect on the solubility of chloroquine. On the other hand, for pressures less than the crossover point, temperature enhancement led to a reduction in the solubility of chloroquine. Moreover, the obtained solubility results were correlated via semi-empirical density-based thermodynamic correlations. Five correlations were studied including: Kumar & Johnston, Mendez-Santiago-Teja, Chrastil, Bartle et al., and Garlapati & Madras. The best performance was obtained for Mendez-Santiago-Teja's correlation in terms of average absolute relative deviation percent (12.0%), while the other examined models showed almost the same performance for prediction of chloroquine solubility.
Nano‐TiO2‐P25‐SO3H as our previous report has successfully been utilized to synthesize azobenzene through the selective conversion of aniline under visible light irradiation. According to PL emission spectra, the immobilizing a solid Brønsted acid of ‐SO3H groups on the pure‐TiO2‐P25 surface with a close interface is an approach to amplify the nano‐TiO2‐P25 response to visible light, which can productively hinder the recombination rate of photogenerated electrons and holes as carriers. Therefore, the photocatalytic activity of the semiconductor is highly likely to increase. Photooxidation of aniline to azobenzene was achieved by applying nano‐TiO2‐P25‐SO3H (Eg = 2.6 eV) that activated by blue photons (λmax = 460 nm), green photons (λmax = 510 nm) and red photons (λmax = 630 nm) which is introducing as a sustainable procedure. Central composite design (CCD) was employed for evaluating the effects of photocatalyst amount, oxidant concentration and irradiation time on the synthesis of azobenzene by this approach. Easily synthesizing, recyclability of the photocatalyst, mild reaction condition and short reaction time could be considered as plus points of this process.
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