Molecular dynamic simulations are performed to investigate the melting process of small three-dimensional clusters (i.e., systems with one and two shells) of classical charged particles trapped in an isotropic parabolic potential. The confined particles interact through a repulsive potential. We find that the ground-state configurations for systems with N=6 , 12, 13, and 38 particles interacting through a Coulomb potential are magic clusters. Such magic clusters have an octahedral or icosahedral symmetry and are found to have a large stability against intrashell diffusion leading to an intershell melting transition prior to the intrashell and radial melting process. For systems with two shells a local radial melting of subshells is found at low temperatures resulting in a structural transition leading to an increased symmetry of the ordered system. Using Lindemann's criterion the different melting temperatures are determined and the influence of the screening of the interparticle interaction was investigated. A normal mode analysis is performed and some of the normal modes are found to be determinantal for the melting process.
Molecular dynamic simulations are performed to investigate the melting process of two-dimensional clusters of classical charged particles trapped in an anisotropic parabolic potential. The confined particles interact through a repulsive potential. We find that the eccentricity of the confinement potential strongly affects the melting pattern of such clusters. Increasing the eccentricity of the confinement potential drives the system through three different melting regimes. Inhomogeneous melting is the typical melting process for anisotropically confined clusters and its appearance in small systems occurs in a distinct form called here internal intershell melting. The latter involves only particles in the center of the cluster while particles on the far left and right of the cluster are still ordered having a much higher melting temperature. Using the Lindemann's criterion the melting temperatures are determined as a function of the different parameters. The internal intershell melting process is found for both long-range (i.e., logarithmic) and short-range (i.e., screened Coulomb) interparticle interaction. Decreasing the range of the interparticle interaction increases the eccentricity of the confinement potential for which internal intershell melting can occur.
The structure of colloids with competing interactions which are confined in a harmonic external trap potential is analyzed numerically by energy minimization in two spatial dimensions. A wealth of different cluster structures is found to be stable including clusters with a fringed outer rim (reminiscent to an ornamental border), clusters perforated with voids, as well as clusters with a crystalline core and a disordered rim. All cluster structures occur in a two-dimensional parameter space. The structural ordering can therefore be efficiently tuned by changing few parameters only providing access to a controlled fabrication of colloidal clusters.
We studied the structural and spectral properties of a classical system consisting of a finite number of particles, moving in two dimensions, and interacting through a repulsive logarithmic potential and held together by an anisotropic harmonic potential. Increasing the anisotropy of the confinement potential can drive the system from a two-dimensional (2D) to a one-dimensional (1D) configuration. This change occurs through a sequence of structural transitions of first and second order which are reflected in the normal mode frequencies. Our results of the ground state configurations are compared with recent experiments and we obtained a satisfactory agreement. The transition from the 1D line structure to the 2D structure occurs through a zigzag transition which is of second order. We found analytical expressions for the eigenfrequencies before the zigzag transition, which allowed us to obtain an analytical expression for the anisotropy parameter at which the zigzag transition occurs as a function of the number of particles in the system.
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