It is now well acknowledged that, after a prototypical loss of coolant accident (LOCA) transient, the resultant mechanical properties of fuel cladding tubes depend strongly on the oxygen content of the residual prior-β layer, as this phase is the only metallic part of the high-temperature oxidized cladding that may show some residual ductility. The aim of this study is to obtain relevant information on the evolution of the mechanical properties, on the one hand, of the prior-β structure as a function of the oxygen content, assuming that there is a critical oxygen content that leads to a ductile-to-brittle failure mode transition at low testing temperatures (20–135°C); and on the other hand, of the α(O) structure as a function of the oxygen content. Sheets of Zircaloy-4, 1 to 3 mm thick, and M5®M5® is a registered trademark of AREVA-NP. advanced alloys from AREVA NP have been studied. To obtain different oxygen contents, they were oxidized at high temperature and then annealed under vacuum in order to reduce the oxide layer. Systematic post-treatment measurements of the oxygen concentration and of its homogeneity within the sheet thickness were performed. The different prior-β and α(O) structures thus obtained have homogeneous oxygen content between ∼0.14 wt. % and 0.9 wt. % and ∼2 wt. % and 7 wt. %, respectively. Such oxygen concentration ranges cover the solubility values that are expected in the β phase and in the α(O) phase at high temperatures typical of LOCA transients. Detailed microstructure investigations were subsequently performed on the prior-β structures since it is considered to be the most important layer when regarding the post-quench mechanical behavior of the material. Continuous cooling temperature (CCT) phase diagrams as a function of the oxygen content were established to correctly interpret the results. Electron backscattered diffraction (EBSD) analysis has then allowed the crystallographic orientations and the morphology of prior-β phase sub-grains to be determined. For each considered prior-β grain, it was possible to interpret the data by taking into account the “Bürgers” crystallographic relationship between the parent β phase and the resultant α phase. Complementary electron probe microanalysis (EPMA) was also used. These last experiments have shown a spatial fluctuation of the oxygen content within the microstructure that depends both on the nominal oxygen content and on the cooling rate. Nanohardness measurements were also performed and correlated with this oxygen spatial partition. These measurements proved to be useful for the understanding of the tensile macroscopic mechanical behavior. Finally, on the one hand, tensile tests were performed on prior-β phase at testing temperatures ranging from −100°C up to 260°C. The ductile-to-brittle temperature transition and the mechanical constitutive laws as a function of the oxygen content were then described. These tests show the existence of a ductile-to-brittle failure mode transition at 20°C for a critical oxygen concentration of ∼0.5 wt. %. A detailed fractographic analysis was performed to assess the failure mechanism. On the other hand, four-point bending tests were conducted on α(O) phase at 25°C and 135°C in order to obtain behavior laws. Preliminary finite element calculations were performed to simulate ring compression tests carried out on multi-layered high-temperature oxidized cladding tubes.

A number of competing failure mechanisms are involved in bearing failure initiation. For well manufactured bearings operating under clean and well controlled running conditions, sub-surface initiated fatigue is the classical initiation form. Three mechanisms dominate the concept of sub-surface induced initiation and growth: (i) The well documented slow structural breakdown of the steel matrix due to accumulation of fatigue damage in a process superficially similar to tempering, (ii) stress induced generation of butterflies by a process enabling the growth of butterfly micro-cracks and accompanying wings at non-metallic inclusions, and (iii) surface induced hydrogen intrusion causing hydrogen-enhanced fatigue damage accumulation in the matrix. The development of butterflies as a function of contact stress, over-rolling, and non-metallic inclusion characteristics is presented, and the influence of metallurgical cleanliness and processing history on this progression is discussed. The results of laboratory conducted tests are compared to results from field applications where premature spallings have occurred. The progression from butterfly micro-cracks to extending cracks with non-etching borders has been studied. Special interest has been paid to the interaction between the non-metallic inclusion composition and morphology and their propensity to generate butterfly wing formations, as this may affect the way that inclusion harmfulness should be judged in rolling bearing steel quality assurance efforts. Complex oxy-sulfides are the main butterfly initiators in today’s bearing steels.

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The hydride stress reorientation behavior and the mechanical properties of irradiated cladding tubes were investigated to evaluate the high-burnup fuel-cladding tube properties in interim dry storage. As for the boiling water reactor ͑BWR͒ Zircaloy-2 ͑Zry-2͒ cladding, the hydride reorientation to the radial direction occurred at relatively low hoop stresses during the hydride reorientation treatment ͑HRT͒, such as less than 70 MPa. The increase of reorientation with hoop stress was not monotonic for the specimens in which a part of the hydrides remained precipitated at the HRT temperature, such as the case for 50GWd/t type cladding at a 300°C HRT. The degree of reorientation depended on the HRT solution temperature rather than on the estimated temperature at which the hydride precipitation occurred under the relatively moderate HRT conditions. In the relatively low cooling rate HRT, the hydride preferential precipitation in the Zr liner increased for Zr lined cladding compared to that in a relatively high cooling rate. The ductility of the specimens after the 300°C HRT showed relatively good correlation to the Polymax index which reflects the length or continuity of the hydrides regardless of their orientation. The ductility of the specimens after the 400°C, 0 MPa, 30°C/h HRT increased in ring compression testing at room temperature compared to no HRT ͑as-irradiated͒ specimens, and it indicated recovery of irradiation damage occurred at the 400°C annealing temperature and affected the ductility of the irradiated Zry-2 cladding. As for the pressurized water reactor Zircaloy-4 cladding, little increase in the radial hydride ratio occurred in a 100 MPa, 340°C or less HRT. On the other hand, the amount and the length of the hydride in the midwall area of the cladding depended on the temperature and the cooling rate from the HRT due to hydrogen migration from the hydride rim area. It is deduced that the ductility in ring compression deformation was affected by the orientation, amount, and length of hydride in the midwall area.

Fatigue information has been reliable in predicting wire critical structural integrity. The aim of this study is to expound on the characterization technique of rotary beam fatigue testing ͑RBT͒. By alternating tension and compression stress states through RBT, it is possible to determine the life expectancy of Nitinol monofilament round wires. Fatigue testing has been employed to characterize the influence of subtle changes in inclusion content, chemistry variations of raw material, ingot transformation temperatures of Nitinol ͑NiTi͒, and surface finish conditions for implant grade wires. Currently, an ASTM standard does not exist that concentrates solely on fatigue testing shape memory alloys. By exploiting part geometry, this testing technique serves to compliment other characterization methods. Evaluation of fracture surfaces has proven useful in diagnosing the factors influencing failures. The utilization of fatigue data and fracture mechanics compliments tensile testing in providing information to the design engineer. Results from studying flexural endurance, statistical Weibull life assessment analysis, fracture analysis, and a determination of stress/strain levels at the site of failure have proven useful in determining desired material properties for next generation medical devices.

Releasable bindings were developed to reduce the risk of lower leg injuries. However, the relationship between the incidence of specific alpine injury groups and the function and calibration of the release system has not been well understood. Over the 32 years between December 1972 and April 2004, the authors conducted a case control study at a northern Vermont ski area involving 17 967 injuries and 3617 uninjured controls. During that time, approximately 6.4 million skier visits were recorded at the area. Injured skiers were treated at clinic in the base lodge and their injuries diagnosed by the clinic staff. Data relating to the accident, the injury, and the equipment used were recorded. The release moments of equipment associated with lower extremity injuries and uninjured controls were measured using a commercially available test device. Case studies of 43 anterior cruciate ligament (ACL) sprains, 79 lower leg injuries, and 99 uninjured controls were conducted using data collected over seven years between December 1997 and April 2004. In terms of quantitative critical defects, 17 % of the control group, 14 % of the ACL group, and 39 % of the lower leg group exhibited release levels more than 30 % above recommended. When qualitative critical defects were considered, 27 % of the control group, 25 % of the ACL group, and 54 % of the lower leg group were found to exhibit one or more defects capable of having a significant effect on equipment function. The authors concluded that sprains, fractures, strains, and contusions of the lower leg among alpine skiers were associated with measurable or observable qualities of the release system. Serious sprains of the knee were not. A substantial reduction of injuries below the knee can be expected if potentially defective equipment can be identified and repaired, or replaced.

Archie's law, which is an empirical relationship between the electrical conductivity of rocks and their porosity, has been used widely for saturated rocks, while Archie's second law has been developed for unsaturated rocks. Both of these laws assume that the rock matrix is non-conducting and the conduction takes place through the pore-solution only. However, not many efforts have been made by the researchers to check suitability and applicability of Archie's law to the saturated or unsaturated states of the soils. Hence, a generalized Archie's law for soils, by incorporating their physical properties, volumetric moisture content, and bulk and pore-solution conductivities, was attempted in this study utilizing the data available in the literature. Further, to demonstrate the validity of this law, four soils with entirely different properties were used. These soils were characterized by conducting conventional laboratory tests, and their bulk and pore-solution conductivities were determined with the help of an impedance analyzer and a pressure membrane extractor.

The previous CEA corrosion code COCHISE provided satisfactory simulations of in-reactor corrosion of the fuel cladding when used in its validity range. In contrast, it could lead to hazardous predictions if applied out of this range due to the strongly linked parameters mainly based on the analysis of French pressurized water reactor (PWR) data. To predict the oxidation kinetics for new operating conditions or new materials, the CEA and EDF decided to develop a new model, named CORCY, which is based on a more phenomenological approach and uses separate parameters deduced from analytical experiments. The aim of this paper is to present the new model for Zircaloy-4 in PWR. The phenomenological approach is described. It is based on out- and in-pile data. Typically, since (1) the oxidation kinetics of zirconium alloys in autoclave are periodic, and (2) the oxide films formed in autoclave, in out-of-pile loop, and in-reactor all exhibit periodic lateral cracks with a period similar to the oxide thickness to transition, the oxidation kinetics in CORCY are characterized by a cyclic repetition of semi-parabolic law. Each model parameter is detailed. They are deduced separately from (a) oxidation tests performed in autoclave on fresh alloys to determine their kinetics; (b) oxidation tests performed in the out-of-pile corrosion loops Corail and Reggae to quantify the effects of thermo-hydraulic conditions; (c) data provided by Testing Material Reactors (OSIRIS and Halden reactor) during isothermal oxidation to determine the effects of irradiation; and (d) oxidation tests performed on pre-hydrided alloys to take into account the accelerated corrosion phase occurring, in reactor, for Zircaloy-4 at high burn-up. After describing both the phenomenological approach and the different model parameters, a comparison of measured and calculated corrosion data from French PWRs at a burn-up up to 65 GWd/tU is provided.