Solid-phase chemical reaction speed control is one of the most essential problems of physics and chemistry of solid bodies. Special attention is paid to the studies of sensitivity and stability of explosive substances (ES). Fundamental issues of studies of azides of heavy metals (AHM) are connected with developing ways of controlling new chemical reactions – solid-phase chain reactions in which electron excitations of a crystal lattice serve as active particles. Applied value is determined by safety issues of ES that include such wide range of problems as storage, transfer, destruction, etc.The result of this work is the use of the experimental results for purposeful change of energetic material
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