Morphological and chemical evidence of ancient life is widespread in sedimentary rocks retrieved from shallow depths in the Earth's crust. Metamorphism is highly detrimental to the preservation of biological information in rocks, thus limiting the geological record in which traces of life might be found. Deformation and increasing pressure/temperature during deep burial may alter the morphology as well as the composition and structure of both the organic and mineral constituents of fossils. However, microspore fossils have been previously observed in intensely metamorphosed rocks. It has been suggested that their small size, and/or the nature of the polymer composing their wall, and/or the mineralogy of their surrounding matrix were key parameters explaining their exceptional preservation. Here, we describe the remarkable morphological preservation of plant macrofossils in blueschist metamorphic rocks from New Zealand containing lawsonite. Leaves and stems can be easily identified at the macroscale. At the microscale, polygonal structures with walls mineralized by micas within the leaf midribs and blades may derive from the original cellular ultrastructure or, alternatively, from the shrinkage during burial of the gelified remnants of the leaves in an abiotic process. Processes and important parameters involved in the remarkable preservation of these fossils during metamorphism are discussed. Despite the excellent morphological preservation, the initial biological polymers have been completely transformed to graphitic carbonaceous matter down to the nanometer scale. This occurrence demonstrates that plant macrofossils may experience major geodynamic processes such as metamorphism and exhumation involving deep changes and homogenization of their carbon chemistry and structure but still retain their morphology with remarkable integrity even if they are not shielded by any hard-mineralized concretion.
The most ancient fossil record contains fundamentally important information on both the diversity and disparity of ancient life. Yet this ancient record is not that easy to decode, due to difficulties mainly pertaining to the impact of the geological history. Thus, the convergence of multiple lines of evidence is seen as necessary to build a robust demonstration of the biogenicity of putative traces of life. Yet, we experimentally show here that abiotic organic cell-like microstructures meeting all the criteria of biogenicity may form in cherts under classical conditions of diagenesis. These organic biomorphs produced from a mixture of RNA and quartz in water exposed to temperature and pressure conditions (200°C, ∼15 bars) exhibit morphological, chemical and isotopic signatures typical of organic microfossils. The results of this study exemplify the pitfalls that Archean palaeontologists may encounter when searching for traces of life in ancient rocks.
The effect of palm fiber on properties of automotive brake composite materials is analyzed. The test procedure followed is JASO C 406, which is for passenger car pads. Tribological properties of three brake pads (6 PF, 8 PF and 10 PF) were tested on full-scale inertia dynamometer for various performance parameters such as pressure-speed sensitivity (effectiveness studies) and Temperature sensitivity (fade and recovery behaviour). A pad undergoes all the testing parameters and maintains its low temperature rise in the disc for three pressure sensitivity and two temperature sensitivity tests. By increasing palm fiber content, hardness, heat swell and specific gravity increases, and also porosity and loss on ignition decreases. Test has been conducted using scanning electron microscope to analyse the all three specimens to evaluate the contact plateaus and wear debris during braking. 8% of palm fiber content in brake pad was found to be superior to 6 PF and 10 PF in most of the important tribological properties.
Abstract:In this paper, a high-friction composite material based on the combination of binder, friction modifiers, fibers and fillers is investigated. In the binder, up to 20% of phenol are replaced by cardanol with various weight ratios of 100/0, 95/5, 90/10, 85/15, 80/20. Cardanol may react both through the phenolic group and the double bond of the side chain yielding addition, condensation and polymerisation reactions that allow the synthesis of tailor-made products and polymers of high value. In the present work, mechanical, thermal and wear characteristics of cardanol based phenolic resin with organic ingredients were manufactured and tested. An analysis of microstructure characteristics of composites was carried out using scanning electron microscope. The effect of environment on the composite was investigated in water, salty water and oil. The results showed that the addition of cardanol reduces the wear resistance and increases the compressibility which reduces the noise propensity.
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