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A silver/polypyrrole/copper oxide (Ag/PPy/CuO) ternary nanocomposite was prepared by sonochemical and oxidative polymerization simple way, in which CuO was decorated with Ag nanoparticles, and covered by polyprrole (PPy) layer. The as prepared materials was characterized by UV-vis-spectroscopy (UV-vis), FT-IR, X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM) with EDX, high resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). Sensing of serotonin (5HT) was evaluated electrocatalyst using polypyrrole/glassy carbon electrode (PPy/GCE), polypyrrole/copper oxide/glassy carbon electrode (PPy/CuO/GCE) and silver/polypyrrole/copper oxide/glassy carbon electrode (Ag/PPy/CuO/GCE). The Ag/PPy/CuO/GCE was electrochemically treated in 0.1MPBS solution through cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The peak current response increases linearly with 5-HT concentration from 0.01 to 250 µmol L and the detection limit was found to be 0.0124 μmol L. It exhibits high electrocatalytic activity, satisfactory repeatability, stability, fast response and good selectivity against potentially interfering species, which suggests its potential in the development of sensitive, selective, easy-operation and low-cost serotonin sensor for practical routine analyses. The proposed method is potential to expand the possible applied range of the nanocomposite material for detection of various concerned electro active substances.

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A novel zinc phthalocyanine/graphene oxide (ZnPh/GO) nanocomposite modified glassy carbon electrode (GCE) was prepared by using sonochemical approach and simple drop casting method. Urease (Urs) was used as the specific enzyme for urea detection and was physically immobilized onto the surface of ZnPh/GO nanocomposite. The fabricated ZnPh/GO/Urs matrix was successfully characterized by UV-vis-spectroscopy, FT-IR spectroscopy, scanning electron microscopy (SEM), raman spectrum, thermogravimetric analysis, cyclic voltammetric (CV) and amperometric techniques. The electrocatalytic performance of the ZnPh/GO/Urs electrode was investigated by urea biosensor. Our results demonstrate that the modified electrode has excellent electrocatalytic activity towards the sensing of urea in 0.1 M phosphate buffer solution (PBS, pH 7.2). The biosensor tolerated a wide linear concentration range for urea from 0.4 to 22 μM (R = 0.991), with a detection limit of 0.034 µM (S/N = 3). The ZnPh/GO/Urs bioectrode has several excellent properties, including a fast response time, high reproducibility and stability.

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