Recently, lead‐free double perovskites have emerged as a promising environmentally friendly photovoltaic material for their intrinsic thermodynamic stability, appropriate bandgaps, small carrier effective masses, and low exciton binding energies. However, currently no solar cell based on these double perovskites has been reported, due to the challenge in film processing. Herein, a first lead‐free double perovskite planar heterojunction solar cell with a high quality Cs2AgBiBr6 film, fabricated by low‐pressure assisted solution processing under ambient conditions, is reported. The device presents a best power conversion efficiency of 1.44%. The preliminary efficiency and the high stability under ambient condition without encapsulation, together with the high film quality with simple processing, demonstrate promise for lead‐free perovskite solar cells.
We use receiver functions calculated for data collected by the INDEPTH‐IV seismic array to image the three‐dimensional geometry of the crustal and upper mantle velocity discontinuities beneath northeastern Tibet. Our results indicate an average crustal thickness of 65 to 70 km in northern Tibet. In addition, we observe a 20 km Moho offset beneath the northern margin of the Kunlun Mountains, a 10 km Moho offset across the Jinsha River Suture and gently northward dipping Moho beneath the Qaidam Basin. A region in the central Qiangtang Terrane with higher than normal crustal Vp/Vs ratio of ∼1.83 can be the result of the Eocene magmatic event. In the Qiangtang Terrane, we observe a significant lithospheric mantle discontinuity beneath the Bangong‐Nujiang Suture at 80 km depth which dips ∼10° to the north, reaching ∼120 km depth. We interpret this feature as either a piece of Lhasa Terrane or remnant oceanic slab underthrust below northern Tibet. We detect a ∼20 km depression of the 660‐km discontinuity in the mantle transition zone beneath the northern Lhasa Terrane in central Tibet, which suggests this phase transition has been influenced by a dense and/or cold oceanic slab. A modest ∼10 km depression of the 410‐km discontinuity located beneath the northern Qiangtang Terrane may be the result of localized warm upwelling associated with small‐scale convection induced by the penetration of the sinking Indian continental lithosphere into the transition zone beneath the central Tibetan Plateau.
An electronic “smart”
contact lens device with high
gas permeability and optical transparency, as well as mechanical compliance
and robustness, offers daily wear capability in eye interfacing and
can have broad applications ranging from ocular diagnosis to augmented
reality. Most existing contact lens electronics utilize gas-impermeable
substrates, electronic components, and interfacial adhesion layers,
which impedes them from applications requiring continuous daily wear.
Here we report on the design and fabrication of an eye interfacing
device with a commercial ocular contact lens as the substrate, metal-coated
nanofiber mesh as the conductor, and in situ electrochemically
deposited poly(3,4-ethylenedioxythiophene) (PEDOT) /poly(styrene sulfonate)
(PSS) as the adhesion material. This hydrogel contact lens device
shows high gas permeability, wettability, and level of hydration,
in addition to excellent optical transparency, mechanical compliance,
and robustness. Using a rabbit model, we found that the animals wearing
these hydrogel contact lens devices continuously for 12 hours showed
a level of corneal fluorescein staining comparable to those wearing
pure hydrogel contact lenses for same period of time, with no obvious
corneal abrasion or irritation, indicating their high level of safety
for continuous daily wear. Finally, full-field electroretinogram (ERG)
recordings on rabbits were carried out to demonstrate the functionality
of this device. We believe that the strategy of integrating nanofiber
mesh-based electronic components demonstrated here can offer a general
platform for hydrogel electronics with the advantages of preserving
the physiological and mechanical properties of the hydrogel, thus
enabling seamless integration with biological tissues and providing
various wearable or implantable sensors with improved biocompatibility
for health monitoring or medical treatment.
Organic-inorganic hybrid perovskite solar cells have been developing rapidly in the past several years, and their power conversion efficiency has reached over 20%, nearing that of polycrystalline silicon solar cells. Because the diffusion length of the hole in perovskites is longer than that of the electron, the performance of the device can be improved by using an electron transporting layer, e.g., TiO2, ZnO and TiO2/Al2O3. Nano-structured electron transporting materials facilitate not only electron collection but also morphology control of the perovskites. The properties, morphology and preparation methods of perovskites are reviewed in the present article. A comprehensive understanding of the relationship between the structure and property will benefit the precise control of the electron transporting process and thus further improve the performance of perovskite solar cells.
The Lei‐Qiong region is the largest igneous province in southern China and may be a surface expression of a mantle plume beneath the region (the Hainan mantle plume). To investigate the existence of the Hainan mantle plume, we used P‐to‐S receiver function to image the major seismic discontinuities beneath this region with a regional dense broadband array. We found that the Moho discontinuity beneath the Leizhou Peninsula, mostly covered by Cenozoic basaltic outcrops, is 10–15 km deeper compared to the adjacent region of Eurasian continental margin, showing a thickened local crust by upwelling mantle materials. Additionally, the imaged 410‐ and 660‐km discontinuities suggest a thinner‐than‐normal mantle transition zone beneath the region, implying that hot materials penetrate through the transition zone from the lower mantle. Both seismic evidences support the existence of the mantle plume, which might be 170–200°C hotter than the surrounding mantle.
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