The use of nanoparticulate zero valent iron (NZVI) in the treatment of inorganic contaminants in landfill leachate and polluted plumes has been the subject of many studies, especially in temperate, developed countries. However, NZVI's potential for reduction of chemical oxygen demand (COD) and treatment of metal ion mixtures has not been explored in detail. We investigated the efficiency of NZVI synthesized in the presence of starch, mercaptoacetic, mercaptosuccinic, or mercaptopropenoic acid for the reduction of COD, nutrients, and metal ions from landfill leachate in tropical Sri Lanka. Synthesized NZVI were characterized with X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis, Fourier transform infrared spectroscopy (FTIR) and Brunauer-Emmett-Teller. Of the samples tested, Starch-NZVI (S-NZVI) and mercaptoacetic-NZVI (MA-NZVI) performed well for treatment both COD and metal mixture. The removal percentages for COD, nitrate-nitrogen, and phosphate from S-NZVI were 50, 88, and 99 %, respectively. Heavy metal removal was higher in S-NZVI (>95 %) than others. MA-NZVI, its oxidation products, and functional groups of its coating showed the maximum removal amounts for both Cu (56.27 mg g(-1)) and Zn (28.38 mg g(-1)). All mercapto-NZVI showed well-stabilized nature under FTIR and XRD investigations. Therefore, we suggest mercapto acids as better agents to enhance the air stability for NZVI since chemically bonded thiol and carbonyl groups actively participation for stabilization process.
Rice is the staple food in Sri Lanka where more than 40% of the farmers are engaged in paddy cultivation producing approximately 4.1 million metric tons of paddies. Cultivation of paddy results in almost the same quantity of rice straw annually out of which a very high proportion is wasted. Hence, there is an enormous potential of utilizing paddy straw for the production of quality compost using landfill bioreactors. In this context, the main objectives of the study were to design a lysimeter simulation of a landfill bioreactor to produce compost from anaerobic digestion using rice straw, animal and green manure and evaluate the quality of the resulting compost. A secondary objective was to minimize possible groundwater pollution with nitrate nitrogen, phosphate and reduce the BOD and COD levels resulting from direct dumping of straw. The lysimeter consisted of a liner made of claypolythene-clay, gas collection system, leachate recirculation system, and main reactor. Altogether 431 kg of straw, 26 kg of cow dung and 32kg of Gliricidia were added to the main reactor. The lysimeter performances were evaluated by estimating pH, nitrate nitrogen, phosphate contents, BOD and COD of both leachate and the permeate. After 200 days of operation, nitrate nitrogen and phosphate of the leak were 1.23 mg/L and 0.03 mg/L, respectively. BOD increased during the first 14 days and it gradually decreased after 200 days. Quality of the compost is tallying with the Sri Lanka standards (SLS) guidelines. The study shows that there is a high potential of producing compost from landfill bioreactor using rice straw. It also revealed that the ground water pollution resulting from nitrate nitrogen and phosphate can significantly be mitigated. Further, it was observed that the levels of BOD and COD can also be reduced.
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