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The present paper reports for the first time the development and application of novel Zn wetted CeO 2 (Zn/ CeO 2 ) composite galvanic zinc coating to combat microbial induced corrosion (MIC). Zinc metal−metal interaction causes the effective incorporation of composite into the galvanic coating and accordingly increases the active sites for antibiofouling activity. The developed coatings are explored for their anticorrosion/antibiofouling characteristics toward MIC induced by cultured seawater consortia. Enhanced antibiofouling activity of the composite galvanic coating is achieved due to the tuned content of 28 wt % Zn and 34 wt % of Ce. High charge transfer resistance as high as 4.0 × 10 14 Ω cm 2 and low double layer capacitance as low as 3.99 × 10 −8 F are achieved by tuning the structure and composition of the coating. The synergistic effect of Zn and Ce ensures the stability and corrosion resistance of the coatings in a corrosive bacterial environment. Evident decreases in the bacterial attachment and biofilm formation are illustrated using antibiofouling assay. The antibiofouling activity is attributed to the effective reduction of Ce 4+ to Ce 3+ and the shuttling characteristics of oxidation state of CeO 2 . This impairs the cellular respiration and results in bacterial death. Thus, it can be used as an effective coating to protect the steel based equipment in corrosive marine environments to combat marine microorganisms and their interactions. The present study also paves the scope for exploration of similar effective protective systems.

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Microcapsules containing oil are potential candidate materials for preparing electrocomposite coatings with excellent tribological properties. In the present study, the preparation of oil-encapsulated microcapsules and electrodeposition of Ni-microcapsule composite coating are presented along with the properties of the coating. In situ interfacial polymerization method was used for the preparation of lubricating oil-encapsulated urea-formaldehyde microcapsules. The synthesized microcapsules were incorporated into the nickel matrix by electrodeposition using Ni-Watts bath. The Ni-composite coating containing microcapsules exhibited smaller Ni grain size, higher microhardness and lower surface roughness compared to plain Ni coating. Electrodeposited Ni coating containing oil-encapsulated microcapsules exhibited improved tribological properties with lower wear loss and coefficient of friction compared to plain nickel coating.

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