Hydrolyzed polyacrylamide (HPAM) is a polymer that extensively used in chemical industry and hydrocarbon extraction and refinery processes, but suffers a common problem of high‐temperature instability. This study improved high‐temperature rheological characteristics of HPAM by using novel graphene oxide (GO) nanosheets. Stable GO dispersions in aqueous HPAM were formulated, and their dynamic and viscoelastic behaviors were studied. The results showed that the addition of GO significantly increased the viscosities and high‐temperature stability of the base polymer fluid, as well as the elastic properties of the dispersion. Spectral data indicated the formation of covalent linkages and electrostatic hydrogen bonding between the GO and the HPAM functional groups, leading to enhanced stability and viscosity that is beneficial for high‐temperature oil recovery. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47582.

Volumetric solar absorption using nanofluids can minimize the thermal loss by trapping the light inside the fluid volume. A strong surface boiling with the underneath fluid still subcooled could have many interesting applications, whose mechanism is however still under strong debate. This work advanced our understanding on volumetric fluid heating by performing a novel experiment under a unique uniform solar heating setup at 280 Suns, with a particular focus on the steam production phenomenon using gold nanofluids. To take the temperature distribution into account, a new integration method was used to calculate the sensible heating contribution. The results showed that the photothermal conversion efficiency was enhanced significantly by gold nanofluids. A three-stage heating scenario was identified and during the first stage most of the energy was absorbed by the surface fluid, resulting in rapid vapor generation with the underneath fluid still subcooled. The condensed vapor analysis showed no nanoparticle escaping even under vigorous boiling conditions. Such results reveal that nanoparticle enabled volumetric solar heating could have many promising applications including clean water production in arid areas where abundant solar energy is available. highlights  Novel experiment was performed for nanofluids at a focused solar flux of 280 Suns. Strong surface evaporation was enabled while the bulk fluid was still subcooled  A new integration method was used to calculate photothermal conversion efficiency  Gold nanofluid (0.04w%) increased photothermal conversion efficiency by 95%. The authors are grateful for all the constructive comments from the reviewer and the Editor. Most of the comments were concerned on the presentation of the work. We have addressed all these concerns in the revised version, and a point-by-point reply is supplied below Reviewer #1:The authors of the present work experimentally investigated the surface boiling and steam production mechanism of gold nanofluids under uniform solar heating of 280 Suns. Various concentrations of gold nanofluids were produced and the generated steam was condensed and tested to reveal the presence of any nanoparticles.The study provides good insight to the surface boiling phenomenon of nanofluids and is in consonant with recent trend of investigation. However, there are several problems that need to be addressed before considering for publication in Applied Energy.1. The Abstract, in its current state is incomplete. It is more like a conclusion and needs to be re-written.Action: the abstract was rewritten with more focus on the novelty 2. The use of "gold nanofluids" should be mentioned in the Title and Abstract.Action: The title was slightly changed to reflect the content, and the was used in the title and the abstract in the revised version.3. In the statement: "For example, researchers [43] from Rice University", the Institution name should be replaced by the Authors' name.Action: T was used to replace the institution name in the revised version....

No abstract

Stacking thin graphene layers into three-dimensional (3D) microscopic structure named graphene nanoplatelets (GNPs) could render much lower-1-1 thermal conductivity (κ) compared with single-layer graphene with ultrahigh κ of around 5000 W•m •K. In this study, decorating GNP surface with nanoparticles (NPs) is proposed to be an effective approach to further push down the lower limit value of κ for GNPs. By introducing six metallic and non-metallic NPs, i.e., Au, Ag, Cu, Fe, Al O and SiO NPs onto the GNP surface, we experimentally corroborate that the κ values of 2 3 2-1-1 5 GNP stacking powders approaches to 0.07 W•m •K , which is 10 magnitudes lower than that of ideal 2D graphene materials. This remarkable reduction could be ascribed to the greatly limited sizes of ideal 2D lattice structure (~2 μm) together with random stacking arrangement and extra phonon scattering sites due to the introduction of heterogeneous NPs. Significantly, it is demonstrated that even distribution and small diameter of NPs are beneficial to thermal transport of stacking GNPs. The progress made so far could pave way to GNP materials with tunable thermal transport performance.

No abstract