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The data on the mineral composition and crystallization conditions of magnesian skarn and magnetite ore at contacts of dolerite with rock salt and dolomite in ore-bearing volcanic-tectonic structures of the Angara-Ilim type have been integrated and systematized. Optical microscopy, scanning and transmission electron microscopy, electron microprobe analysis, electron paramagnetic resonance, Raman and IR spectroscopy, and methods of mineralogical thermometry were used for studying minerals and inclusions contained therein. The most diverse products of metasomatic reactions are found in the vicinity of a shallow-seated magma chamber that was formed in Lower Cambrian carbonate and saliferous rocks under a screen of terrigenous sequences. Conformable lodes of spinel-forsterite skarn and calciphyre impregnated with magnesian magnetite replaced dolomite near the central magma conduit and apical portions of igneous bodies. At the postmagmatic stage, the following mineral assemblages were formed at contacts of dolerite with dolomite: (1) spinel + fassaite + forsterite + magnetite ( T = 820-740°C), (2) phlogopite + titanite + pargasite + magnetite ( T = 600-500°C), and (3) clinochlore + serpentine + pyrrhotite ( T = 450°C and lower). Rock salt is transformed at the contact into halitite as an analogue of calciphyre. The specific features of sedimentary, contact-metasomatic, and hydrothermal generations of halite have been established. The primary sedimentary halite contains solid inclusions of sylvite, carnallite, anhydrite, polyhalite, quartz, astrakhanite, and antarcticite; nitrogen, methane, and complex hydrocarbons have been detected in gas inclusions; and the liquid inclusions are largely aqueous, with local hydrocarbon films. The contact-metasomatic halite is distinguished by a fine-grained structure and the occurrence of anhydrous salt phases ( CaCl 2 · KCl, CaCl 2 , n MgCl 2 · m CaCl 2 ) and high-density gases ( CO 2 , H 2 S, N 2 , CH 4 , etc.) as inclusions. The low-temperature hydrothermal halite, which occurs in skarnified and unaltered silicate rocks and in ore, is characterized by a low salinity of aqueous inclusions and the absence of solid inclusions. The composition and aggregative state of inclusions in halite and forsterite indicate that salt melt-solution as a product of melting and dissolution of salt was the main agent of high-temperature metasomatism. Its total salinity was not lower than 60%. The composition and microstructure of magnetite systematically change in different mineral assemblages. Magnetite is formed as a result of extraction of iron together with silicon and phosphorus from dolerite. The first generation of magnetite is represented by mixed crystals, products of exsolution in the Fe-Mg-Al-Ti-Mn-O system. The Ti content is higher at the contact of dolerite with rock salt, whereas, at the contact with dolomite, magnetite is enriched in Mg. The second generation of magnetite does not contain structural admixtures. The distribution of boron minerals and complex crystal hydrates shows that ...

Anhydrous chlorides-CaCl 2 , and KCaCl 3 (chlorocalcite) were identified as mineral inclusions in halite from the Siberian Large Igneous Province at the contact of magmatic intrusions and evaporates. Chlorocalcite was also found as daughter mineral in polyphase hypersaline inclusions. While Raman spectra of KCaCl 3 (chlorocalcite) in natural inclusions are similar to spectra of synthetic analogue, the Raman spectra of natural CaCl 2 do not correspond to the published Raman spectra of synthetic CaCl 2. Simulations of Raman spectra using ab initio density-functional theory (DFT) allowed us to calculate the spectra of individual polymorphs of CaCl 2 and to discriminate anhydrous CaCl 2 phases in natural inclusions and synthetic CaCl 2. In the spectrum of the Pbcn polymorph of CaCl 2 twelve different peaks could be identified at 74,