The crystallographic and magnetic properties of CaRu 1−x Mn x O 3 ͑0 Յ x Յ 1.0͒ were investigated in detail by x-ray powder diffraction, magnetization, and magnetic Compton scattering measurements. The lattice parameters show considerable deviation from Vegard's law. Ferromagnetism appears at a relatively large Mn concentration ͑x Ն 0.2͒, and the magnetization and the Curie temperature have a maximum at a Mn content near x = 0.7. The magnetic Compton scattering measurement revealed that Mn makes a dominant contribution to the magnetization and the Mn moment is antiparallel to the Ru moment, which is induced by Mn doping. The anomalous change in the unit cell volume and the occurrence of ferromagnetism were discussed on the basis of the mixed-valence model of Mn 3+ , Mn 4+ , Ru 4+ , and Ru 5+ ions. The Mn-composition dependence of the spontaneous magnetization was explained semiquantitatively assuming ͑1͒ ferromagnetic coupling between Mn 3+ and Mn 4+ ions, ͑2͒ antiferromagnetic coupling between Ru 5+ and Mn ions, and ͑3͒ the theoretical spin moments of Mn 3+ , Mn 4+ , and Ru 5+ . The ferromagnetic interaction between Mn 3+ and Mn 4+ ions seems to make a dominant contribution to the Curie temperature. The CaRu 1−x Mn x O 3 system is considered to be a ferrimagnet induced through competition between the ferromagnetic interaction between Mn ions and the antiferromagnetic interaction between Ru 5+ and Mn ions.

No abstract

No abstract

No abstract

The crystallographic, magnetic, and electric properties of CaMn(1-x)Ir(x)O(3) (0≤x≤0.6) were investigated. The lattice constants increase with increasing content of Ir. Specimens of 0.05≤x≤0.2 show antiferromagnetic behavior; however, ferromagnetism is observed for specimens of 0.3≤x≤0.6. T(N) decreases as the Ir content increases. T(N) is superseded by T(C) without passing 0 K and T(C) continues to increase in the ferromagnetic composition range. The effective moment μ(eff) decreases as the Ir content increases. The Weiss temperature is negative for small x; however, it continues to increase while changing its sign at about x = 0.3. The results were explained by assuming a mixed valence state of Mn(3+), Mn(4+), Ir(4+), and Ir(5+) ions. The composition dependence of μ(eff) could be explained qualitatively using the ion fractions estimated from the Ir content dependence of the unit cell volume. Experimental results suggest the coexistence of antiferromagnetic and ferromagnetic phases. When the volume fraction of the ferromagnetic phase dominates that of the antiferromagnetic phase, the system seems to show ferromagnetism.