The effect of tempering on the mechanical properties, structure, and dispersion of secondary phase particles is studied in 0.4%C-2%Si-1%Cr-1%Mo-VNb steel. This steel austenitized at 900 °C with subsequent water quenching exhibits a yield stress of 1445 MPa and a lath martensite structure with MX particles of ~40 nm located in matrix and boundary M6C carbides of ~210 nm. Tempering in the temperature interval of 200–400 °C provides a yield stress of 1625 MPa due to the precipitation of ε-carbide and cementite within laths. The yield stress decreases to 1415 and 1310 MPa after tempering at 500 and 650 °C, respectively, due to the replacement of matrix carbides by boundary M23C6 carbide. A Charpy V-notch impact energy of ~12 J/cm2 is almost independent from tempering temperatures of up to 400 °C and increases up to ~33 J/cm2 after tempering at 650 °C due to decreased yield stresses and increased plasticity.

An effect of tempforming on the microstructure, the carbide precipitation, and the strengthening mechanisms of high-strength low-alloyed steel has been analyzed. The quenched steel was subjected to 1 h tempering at a temperature of 873 K, 923 K, or 973 K followed by plate rolling at the same temperature. Tempforming resulted in the formation of an ultrafine grained lamellar-type microstructure with finely dispersed carbides of (Nb,V)C, Fe3C and Cr23C6. A decrease in tempforming temperature resulted in a reduction of the transverse grain size from 950 nm to 350 nm. Correspondingly, the size of Fe3C/Cr23C6 particles decreased from 90 nm to 40 nm while the size of (Nb,V)C particles decreased from 17 nm to 4 nm. Refining the tempformed microstructure with a decrease in thetempforming temperature provided an increase in the yield strength from 690 MPa to 1230 MPa.

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The effect of tempering after water quenching on the strength and fracture toughness of two steels with chemical compositions of 0.34%C-1.77%Si-1.35Mn-0.56%Cr-0.2%Mo-0.04%Nb-0.03Ti-0.002B and 0.44%C-1.81%Si-1.33%Mn-0.82%Cr-0.28%Mo was examined. The last steel exhibits quenching embrittlement in an as-quenched condition. At a tempering temperature of 280 °C, the precipitation of transition η–Fe2C carbides in martensitic matrix leads to increasing fracture toughness and eliminates quench embrittlement in the steel with 0.44 wt.%C. Tempered martensite embrittlement at 400 °C appears as decreased values of the Charpy V-notch impact energy, ductility and the product of strength and elongation, σB´δ (MPa´%) and is attributed to increased effective grain size for fracture, mainly. The precipitation of boundary cementite takes place at tempering at 500 °C and provides increased ductility and fracture toughness despite a decohesion along carbide/ferrite interfaces. The low severity of TME in Si-rich low-alloy medium carbon steels is attributed to the suppression of boundary cementite precipitation at tempering temperatures ≤400 °C.

Quenching and partitioning (Q&P) treatments were applied to 0.25C steel to produce the microstructures that exhibit an improved balance of mechanical properties. The simultaneous bainitic transformation and carbon enrichment of retained austenite (RA) during the partitioning stage at 350 °C result in the coexistence of RA islands with irregular shapes embedded in bainitic ferrite and film-like RA in the martensitic matrix. The decomposition of coarse RA islands and the tempering of primary martensite during partitioning is accompanied by a decrease in the dislocation density and the precipitation/growth of η-carbide in the lath interiors of primary martensite. The best combinations of a yield strength above 1200 MPa and an impact toughness of about 100 J were obtained in the steel samples quenched to 210–230 °C and subjected to partitioning at 350 °C for 100–600 s. A detailed analysis of the microstructures and the mechanical properties of the steel subjected to Q&P, water quenching, and isothermal treatment revealed that the ideal strength–toughness combinations could be attributed to the mixture of the tempered lath martensite with finely dispersed and stabilized RA and the particles of η-carbide located in the lath interiors.