Nonionic water-in-oil (w/o)−microemulsions of the type water/c-hexane, n-hexane/Igepal were examined by SANS in both shell and core contrast. Variation of the water to surfactant ratio W 0 in the droplet regime yields a linear relation between W 0 and the droplet water core radius and R/nm = 0.19 W 0 + 0.70. Small angle neutron scattering (SANS) data for W 0 = 10 samples show that droplet aggregation occurs with a fractal dimension of D ≤ 1.3 as a percolation-like transition is crossed by decreasing temperature. Data analysis and model calculations, done in both q and r space, are consistent with the formation of linear aggregates of discrete spherical droplets.

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