The distribution of geochemical species in the Earth's interior is largely controlled by fractional melting and crystallization processes that are intimately linked to the thermal state and evolution of the mantle. The existence of patches of dense partial melt at the base of the Earth's mantle, together with estimates of melting temperatures for deep mantle phases and the amount of cooling of the underlying core required to maintain a geodynamo throughout much of the Earth's history, suggest that more extensive deep melting occurred in the past. Here we show that a stable layer of dense melt formed at the base of the mantle early in the Earth's history would have undergone slow fractional crystallization, and would be an ideal candidate for an unsampled geochemical reservoir hosting a variety of incompatible species (most notably the missing budget of heat-producing elements) for an initial basal magma ocean thickness of about 1,000 km. Differences in 142Nd/144Nd ratios between chondrites and terrestrial rocks can be explained by fractional crystallization with a decay timescale of the order of 1 Gyr. These combined constraints yield thermal evolution models in which radiogenic heat production and latent heat exchange prevent early cooling of the core and possibly delay the onset of the geodynamo to 3.4-4 Gyr ago.

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The rate at which heat is extracted across the core mantle boundary (CMB) is constrained by the requirement of dynamo action in the core. This constraint can be computed explicitly using the entropy balance of the core and depends on the thermal conductivity, whose value has been revised upwardly. A high order model (fourth degree polynomial of the radial position) for the core structure is derived and the implications for the core cooling rate and thermal evolution obtained, using the recent values of the thermal conductivity. For a thermal conductivity increasing with depth as proposed by some of these recent studies, a CMB heat flow equal to the isentropic value (13.25TW at present) leads to a 700 km thick layer at the top of the core where a downward convective heat flow is necessary to maintain an isentropic and well mixed average state. Considering a CMB heat flow larger than the well mixed isentropic value leads to an inner core less than 700 Myr old and the thermal evolution of the core is largely constrained by the conditions for dynamo action without an inner core. Analytical calculations for that period show that a CMB temperature larger than 7000 K must have prevailed 4.5 Gyr ago if the geodynamo has been driven by thermal convection for that whole time. This raises questions regarding the onset of the geodynamo and its continuous operation for the last 3.5 Gyr. Implications regarding the evolution of a basal magma ocean are also considered.

International audienceAlthough it is known that the geodynamo has been operating for at least 3.2 Ga, it remains difficult to infer the intensity, dipolarity and stability (occurrence of reversals) of the Precam-brian magnetic field of the Earth. In order to assist the interpretation of palaeomagnetic data, we produce models for the long-term evolution of the geodynamo by combining core ther-modynamics with a systematic scaling analysis of numerical dynamo simulations. We update earlier dynamo scaling results by exploring a parameter space, which has been extended in order to account for core aspect ratios and buoyancy source distributions relevant to Earth in the Precambrian. Our analysis highlights the central role of the convective power, which is an output of core thermodynamics and the main input of our updated scalings. As the thermal evolution of the Earth's core is not well known, two end-member models of heat flow evolution at the core–mantle boundary (CMB) are used, respectively, terminating at present heat flows of 11 TW (high-power scenario) and 3 TW (low power scenario). The resulting models predict that until the appearance of the inner core, a thermal dynamo driven only by secular cooling, and without any need for radioactive heating, can produce a dipole moment of strength comparable to that of the present field, thus precluding an interpretation of the oldest palaeomagnetic records as evidence of the inner core presence. The observed lack of strong long-term trends in palaeointensity data throughout the Earth's history can be rationalized by the weakness of palaeointensity variations predicted by our models relatively to the data scatter. Specifically, the most significant internal magnetic field increase which we predict is associated to the sudden power increase resulting from inner core nucleation, but the dynamo becomes deeper-seated in the core, thus largely cancelling the increase at the core and Earth surface, and diminishing the prospect of observing this event in palaeointensity data. Our models additionally suggest that the geodynamo has lied close to the transition to polarity reversals throughout its history. In the Precambrian, we predict a dynamo with similar dipolarity and less frequent reversals than at present times, due to conditions of generally lower convective forcing. Quantifying the typical CMB heat flow variation needed for the geodynamo to cross the transition from a reversing to a non-reversing state, we find that it is unlikely that such a variation may have caused superchrons in the last 0.5 Ga without shutting down dynamo action altogether

The composition and state of Earth's core, located deeper than 2,900 km from the surface, remain largely uncertain. Recent static experiments on iron and alloys performed up to inner core pressure and temperature conditions have revealed phase relations and properties of core materials. These mineral physics constraints, combined with theoretical calculations, continue to improve our understanding of the core, in particular the crystal structure of the inner core and the chemical composition, thermal structure and evolution, and possible stratification of the outer core.

The Earth's core is about ten per cent less dense than pure iron (Fe), suggesting that it contains light elements as well as iron. Modelling of core formation at high pressure (around 40-60 gigapascals) and high temperature (about 3,500 kelvin) in a deep magma ocean predicts that both silicon (Si) and oxygen (O) are among the impurities in the liquid outer core. However, only the binary systems Fe-Si and Fe-O have been studied in detail at high pressures, and little is known about the compositional evolution of the Fe-Si-O ternary alloy under core conditions. Here we performed melting experiments on liquid Fe-Si-O alloy at core pressures in a laser-heated diamond-anvil cell. Our results demonstrate that the liquidus field of silicon dioxide (SiO) is unexpectedly wide at the iron-rich portion of the Fe-Si-O ternary, such that an initial Fe-Si-O core crystallizes SiO as it cools. If crystallization proceeds on top of the core, the buoyancy released should have been more than sufficient to power core convection and a dynamo, in spite of high thermal conductivity, from as early on as the Hadean eon. SiO saturation also sets limits on silicon and oxygen concentrations in the present-day outer core.

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