Abstract:Temporal wet-season trends from 1987 to 1998 of total N and total P concentrations (TN and TP, respectively) in 14 tributaries to the Swan-Canning Estuary in Western Australia were evaluated using the Mann-Kendall or Seasonal kendall tests. Six of the catchments drained clay soils primarily on the Darling Plateau, which borders the sandy coastal plain on the east; two rural catchments drained the coastal plain; and six urban catchments drained the coastal plain. Generally, TN and TP were lower in tributaries draining clay soils than in tributaries draining siliceous sandy soils. Annual median TN and TP were relatively constant and no trends were detected in tributaries draining clay soils. TN and TP were higher (median TN D 1Ð6 and TP D 0Ð1 mg l 1 ) and more variable temporally in tributaries draining the coastal plain. Statistically significant (˛< 0Ð01) TN trends were detected in 50% of the urban coastal plain tributaries and most were decreasing ( 0Ð07 to C0Ð53 mg l 1 year 1 ). Decreasing TP trends were detected at the two rural coastal plain tributaries and two of the urban drains ( 0Ð01 to 0Ð15 mg l 1 year 1 over periods from 5 to 12 years). Flow adjustment of TN and TP was responsible for removing trends in the raw data at some sites. The inter-annual variability of TN and TP of coastal plain tributaries was also related to the proximity of the water table to the land surface, which in turn was related to the annual precipitation. Fixed-interval sampling may be able to detect TN and TP changes associated with the implementation of management strategies in sandy coastal plain catchments. Tributary sampling during rainstorms and continuous monitoring of discharge are needed to better define processes controlling nutrient flux and concentration variability, and to detect trends in the urban catchments and the clay soil catchments, primarily those draining the Darling Plateau.
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