Inorganic Chemistry in taking spectra. Some metal complex syntheses were performed by P. B. Bowman. Elemental analyses were done by C. S. Yeh. This research was supported in part by The United States Atomic Energy Commission under Contract AT(11-1)-1222.Contribution from the Departments of Chemistry,
The nu(CN) vibrational spectra of cyanide groups bridging two metal atoms present a confused picture. Factors relevant to the interpretation of the available data are reviewed. Some mechanisms for frequency change, relative to the corresponding terminal species, are made more quantitative than previously described, and others are highlighted for the first time. The kinematic effect is much less important than previously assumed. It seems that an effect responsible for the major part of the frequency increase upon bridging commonly observed is the cation electric field, together with concomitant relaxation (the IVSE model). However, a contribution may well come from the change in the sigma bonding in the CN unit.
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