Utilizing infrared vibrational spectroscopy we have investigated dimerized two-dimensional organic salts in order to search for possible charge redistribution that might constitute electronic dipoles and ferroelectricity: the quantum spin liquid κ-(BEDT-TTF) 2 Cu 2 (CN) 3 [BEDT-TTF: bis-(ethylenedithio)tetrathiafulvalene], the antiferromagnetic Mott insulator κ-(BEDT-TTF) 2 Cu[N(CN) 2 ]Cl, and the superconductor κ-(BEDT-TTF) 2 Cu[N(CN) 2 ]Br. None of them exhibit any indication of charge disproportionation. Upon cooling to low temperatures all BEDT-TTF molecules remain homogeneously charged within ±0.005e. No modification in the charge distribution is observed around T = 6 K where a low-temperature anomaly has been reported for the spin-liquid material κ-(BEDT-TTF) 2 Cu 2 (CN) 3 . In this compound the in-plane optical response and vibrational coupling are rather anisotropic, indicating that the tilt of the BEDT-TTF molecules in c direction and their coupling to the anion layers has to be considered in the explanation of the electromagnetic properties.
The orthorhombic rare-earth manganite compounds RMnO 3 show a global magnetic order for < T T N , and several representatives are multiferroic with a cycloidal spin ground state order for. We deduce from the temperature dependence of spin-phonon coupling in Raman spectroscopy for a series of RMnO 3 compounds that their spin order locally persists up to about twice T N . Along the same line, our observation of the persistence of the electromagnon in GdMnO 3 up to » T 100 K is attributed to a local cycloidal spin order for > T T cycl , in contrast to the hitherto assumed incommensurate sinusoidal phase in the intermediate temperature range. The development of the magnetization pattern can be described in terms of an order-disorder transition at T cycl within a pseudospin model of localized spin cycloids with opposite chirality.-Eu x 1 Y x MnO 3 or
We report the observation of tens of minor lines of the combinational spin-flip Raman scattering in aCdTe:Mn quantum well by means of the high-resolution optical spectroscopy. Classification of this manifold leads to four characteristic values of energy, that correspond to four different types of pair clusters of Mn ions: the nearest, second, third etc. neighbors. All the four energies show up in a single experiment with a very high precision, providing experimental grounds for a deeper understanding of the d-d exchange interactions in a diluted magnetic semiconductor and demonstrating the capacity of the employed method. Notably, the major nearest-neighbor exchange constant
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