Piezoelectric materials are widely referred to as "smart" materials because they can transduce mechanical pressure acting on them to electrical signals and vice versa. They are extensively utilized in harvesting mechanical energy from vibrations, human motion, mechanical loads, etc., and converting them into electrical energy for low power devices. Piezoelectric transduction offers high scalability, simple device designs, and high-power densities compared to electro-magnetic/static and triboelectric transducers. This review aims to give a holistic overview of recent developments in piezoelectric nanostructured materials, polymers, polymer nanocomposites, and piezoelectric films for implementation in energy harvesting. The progress in fabrication techniques, morphology, piezoelectric properties, energy harvesting performance, and underpinning fundamental mechanisms for each class of materials, including polymer nanocomposites using conducting, non-conducting, and hybrid fillers are discussed. The emergent application horizon of piezoelectric energy harvesters particularly for wireless devices and self-powered sensors is highlighted, and the current challenges and future prospects are critically discussed.
Tin whiskers pose an electrical reliability risk in the form of potential short circuits. This problem was solved in the past by adding a few percent of Pb during Sn electroplating, but with the ban on Pb in Europe and elsewhere, it has resurfaced. While various mitigation strategies have been formulated based on known whisker growth mechanisms, the electronic industry is still awaiting a satisfactory solution to the whisker growth problem in Pb-free electronics. Recent advances in the understanding and mitigation of whiskers are reviewed herein. The effects of various alloying elements/dopants are discussed in terms of the mechanisms that impact whisker growth kinetics and mitigation. Most recently, indium addition to Sn has been found to eliminate whiskers with even better mitigation performance than Pb addition. The mechanisms are discussed, and the important role of indium on the surface oxide and subsurface enrichment is highlighted.
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