We look ahead from the frontiers of research on ice dynamics in its broadest sense; on the structures of ice, the patterns or morphologies it may assume, and the physical and chemical processes in which it is involved. We highlight open questions in the various fields of ice research in nature; ranging from terrestrial and oceanic ice on Earth, to ice in the atmosphere, to ice on other solar system bodies and in interstellar space.

a b s t r a c tMolecular hydrogen is the most abundant molecule in the universe. It is the first one to form and survive photo-dissociation in tenuous environments. Its formation involves catalytic reactions on the surface of interstellar grains. The micro-physics of the formation process has been investigated intensively in the last 20 years, in parallel of new astrophysical observational and modeling progresses. In the perspectives of the probable revolution brought by the future satellite JWST, this article has been written to present what we think we know about the H 2 formation in a variety of interstellar environments.

MIPSGAL is a 278 deg 2 survey of the inner Galactic plane using the Multiband Infrared Photometer for Spitzer aboard the Spitzer Space Telescope. The survey field was imaged in two passbands, 24 and 70 μm with resolutions of 6″ and 18″, respectively. The survey was designed to provide a uniform, well-calibrated and well-characterized data set for general inquiry of the inner Galactic plane and as a longer-wavelength complement to the shorter-wavelength Spitzer survey of the Galactic plane: Galactic Plane Infrared Mapping Survey Extraordinaire. The primary science drivers of the current survey are to identify all high-mass (M > 5 M ⊙) protostars in the inner Galactic disk and to probe the distribution, energetics, and properties of interstellar dust in the Galactic disk. The observations were planned to minimize data artifacts due to image latents at 24 μm and to provide full coverage at 70 μm. Observations at ecliptic latitudes within 15°of the ecliptic plane were taken at multiple epochs to help reject asteroids. The data for the survey were collected in three epochs, 2005 September-October, 2006 April, and 2006 October with all of the data available to the public. The estimated point-source sensitivities of the survey are 2 and 75 mJy (3 σ) at 24 and 70 μm, respectively. Additional data processing was needed to mitigate image artifacts due to bright sources at 24 μm and detector responsivity variations at 70 μm due to the large dynamic range of the Galactic plane. Enhanced data products including artifact-mitigated mosaics and point-source catalogs are being produced with the 24 μm mosaics already publicly available from the NASA/IPAC Infrared Science Archive. Some preliminary results using the enhanced data products are described.

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Sulfur appears to be depleted by an order of magnitude or more from its elemental abundance in star-forming regions. In the last few years, numerous observations and experiments have been performed in order to to understand the reasons behind this depletion without providing a satisfactory explanation of the sulfur chemistry towards high-mass star-forming cores. Several sulfur-bearing molecules have been observed in these regions, and yet none are abundant enough to make up the gas-phase deficit. Where, then, does this hidden sulfur reside? This paper represents a step forward in our understanding of the interactions among the various S-bearing species. We have incorporated recent experimental and theoretical data into a chemical model of a hot molecular core in order to see whether they give any indication of the identity of the sulfur sink in these dense regions. Despite our model producing reasonable agreement with both solid-phase and gas-phase abundances of many sulfur-bearing species, we find that the sulfur residue detected in recent experiments takes up only ∼6 per cent of the available sulfur in our simulations, rather than dominating the sulfur budget.

This paper describes the design and operation of a position-sensitive coincidence spectrometer which detects the pairs of ions formed in the bimolecular reactions of dications. In the experiment a pulsed, energy-selected beam of dications interacts with a neutral collision gas in the source region of a time-of-flight mass spectrometer. Product ions formed in these interactions are detected in coincidence at a position-sensitive detector. From the resulting data, we can derive the velocity vectors, in the centre of mass frame, of both of the product ions. From these pairs of vectors, detailed information on the reaction dynamics and kinematics can be extracted. The power of the new technique has been demonstrated by a study of the electron transfer reaction between Ar2+ and He, which shows that the 3P and 1D states of Ar2+ react with He, via electron transfer, to form pairs of singly charged ions with markedly different angular distributions.