Das bei der Thermolyse des Diazirins (I) in Cyclohexan bei 200‐220°C entstehende Carben reagiert mit der Ausgangsverbindung zum Azin (II), mit dem Lösungsmittel zum Cyclohexyladamantan (IV); außerdem entstehen geringe Mengen des Dehydroadamantans (III).
Die alicyclischen Ketone bzw. Acetophenon (I) reagieren mit I‐Iydroxylamin‐O‐schwefelsäure zu den instabilen Sulfoketoximen, die mit NH3 in Form ihrer stabilen Ammoniumsalze (II) isoliert werden.
2000 bridged compounds bridged compounds Q 0060 10 -095 Horner-Emmons Reaction in the Synthesis of Esters of Unsaturated Acids from Adamantane Series and Related Carcass Compounds. -Horner-Emmons reaction proves to be in principle suitable for the preparation of esters of unsaturated C-2 to C-3 carboxylic acids [cf. (III), (V)] containing bulky carcass substituents at the multiple bond. -(MIRYAN, N. I.; ISAEV, S. D.; KOVALEVA, S. A.; PETUKH, N. V.; DVORNIKOVA, E. V.; KARDAKOVA, E. V.; YURCHENKO, A. G.; Russ.
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