Carbonate rocks are important hydrocarbon reservoir rocks with complex textures and petrophysical properties (porosity and permeability) mainly resulting from various diagenetic processes (compaction, dissolution, precipitation, cementation, etc.). These complexities make prediction of reservoir characteristics (e.g. porosity and permeability) from their seismic properties very difficult. To explore the relationship between the seismic, petrophysical and geological properties, ultrasonic compressional‐ and shear‐wave velocity measurements were made under a simulated in situ condition of pressure (50 MPa hydrostatic effective pressure) at frequencies of approximately 0.85 MHz and 0.7 MHz, respectively, using a pulse‐echo method. The measurements were made both in vacuum‐dry and fully saturated conditions in oolitic limestones of the Great Oolite Formation of southern England. Some of the rocks were fully saturated with oil. The acoustic measurements were supplemented by porosity and permeability measurements, petrological and pore geometry studies of resin‐impregnated polished thin sections, X‐ray diffraction analyses and scanning electron microscope studies to investigate submicroscopic textures and micropores. It is shown that the compressional‐ and shear‐wave velocities (Vp and Vs, respectively) decrease with increasing porosity and that Vp decreases approximately twice as fast as Vs. The systematic differences in pore structures (e.g. the aspect ratio) of the limestones produce large residuals in the velocity versus porosity relationship. It is demonstrated that the velocity versus porosity relationship can be improved by removing the pore‐structure‐dependent variations from the residuals. The introduction of water into the pore space decreases the shear moduli of the rocks by about 2 GPa, suggesting that there exists a fluid/matrix interaction at grain contacts, which reduces the rigidity. The predicted Biot–Gassmann velocity values are greater than the measured velocity values due to the rock–fluid interaction. This is not accounted for in the Biot–Gassmann velocity models and velocity dispersion due to a local flow mechanism. The velocities predicted by the Raymer and time‐average relationships overestimated the measured velocities even more than the Biot model.

Ultrasonic compressional‐ and shear‐wave attenuation measurements have been made on 40, centimetre‐sized samples of water‐ and oil‐saturated oolitic limestones at 50 MPa effective hydrostatic pressure (confining pressure minus pore‐fluid pressure) at frequencies of about 0.85 MHz and 0.7 MHz respectively, using the pulse‐echo method. The mineralogy, porosity, permeability and the distribution of the pore types of each sample were determined using a combination of optical and scanning electron microscopy, a helium porosimeter and a nitrogen permeameter. The limestones contain a complex porosity system consisting of interparticle macropores (dimensions up to 300 microns) and micropores (dimensions 5–10 microns) within the ooids, the calcite cement and the mud matrix. Ultrasonic attenuation reaches a maximum value in those limestones in which the dual porosity system is most fully developed, indicating that the squirt‐flow mechanism, which has previously been shown to occur in shaley sandstones, also operates in the limestones. It is argued that the larger‐scale dual porosity systems present in limestones in situ could similarly cause seismic attenuation at the frequencies of field seismic surveys through the operation of the squirt‐flow mechanism.

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Over the past eight years the Geophysics Group of the Postgraduate Research Institute for Sedimentology has developed equipment for accurately measuring the seismic properties of centimetre-size samples of sedimentary rocks at ultrasonic frequencies

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